Poly(Phenylene Sulfide)의 고분자량화 및 Sulfone 유도체와의 중합 반응

박이순; 김기현; 이수창; 한상규; 차일훈

Polymer(Korea), Vol.16, No.6, 687-692, November, 1992

Export Citation

Poly(Phenylene Sulfide)의 고분자량화 및 Sulfone 유도체와의 중합 반응

Polymerization and Copolymerization of Poly(p-phenylene sulfide) and Poly(p-phenylene sulfide/sulfone)

박이순, 김기현, 이수창, 한상규, 차일훈

초록

Poly(phenylene sulfide), PPS의 고분자량화를 위하여 공중합법 및 상전이 촉매 효과를 조사하였다. 먼저 sodium sulfide(Na₂S·9H₂O)를 p-dichlorobenzene(DCB)와 중합시켜 PPS를 그리고 4-chlorophenylsulfone(CPS)와 중합시켜 poly(phenylene sulfide/sulfone), PPSS를 얻는 단독중합 조건에 대해 조사하였다. 소량의 CPS를 DCB와 직접 공중합하기 보다 coupling 반응을 통하여 PPS의 분자량을 증가시킬 수 있음을 알았다. 또 crown ether들을 상전이 촉매로 사용할 때 PPS의 분자량이 증가함을 확인하였으나 그 효과는 lithium acetate 첨가제를 NMP 용매에 투입할 때 보다 크지 않음을 알 수 있었다.

For the improvement of molecular weight of poly(phenylene sulfide), PPS, copolymerization method and phase transfer catalyst as additive were investigated. As a preliminary experiment the optimum homopolymerization conditions of PPS from p-dichlorobenzene(DCB) and Na₂S·9H₂O and poly(phenylene sulfide/sulfone), PPSS from 4-chlorophenylsulfone(CPS) and Na₂S·9H₂O were examined. The use of minor amount of CPS comonomer with DCB in a coupling type reaction was found to give higher molecular weight polymer than direct copolymerization or homopolymerization of PPS. The addition of 1/50 amount of phase transfer catalysts such as 15-crown-5, 18-crown-6, dibenzo 18-crown-6, dicyclohexano 18-crown-6 based on sodium sulfide also improved the molecular weight of PPS. The effect, however, was not so great as that of lithium acetate added equimolar amount of Na₂S·9H₂O into NMP solvent.

[References]

Margolis JM, "Engineering Thermoplastics," Marcel Dekker (1985)
Hill HW, Brady DG, Chem. Tech., 49, 33 (1977)
Brady DG, J. Appl. Polym. Sci., 20, 2541 (1976)
Short JN, Hill HW, Chem. Tech., 2, 481 (1972)
Sandler SR, Wolf Karo, "Polymer Syntheses," 3, 81, Academic Press (1980)
Encyclopedia of Chemical Technology, 3rd ed., 18, 793 (1982)
Lovell PA, Still RH, Makromol. Chem., 188, 111 (1987)
Edmonds JT, Hill HW, U.S. Patent, 3,354,129 (1967)
Edmonds JT, Hill HW, U.S. Patent, 3,524,835 (1970)
Fahey DR, Ash CE, Macromolecules, 24, 4242 (1991)
Tsuchida E, Macromolecules, 23, 930 (1990)
Solomon OF, Ciuta IZ, J. Appl. Polym. Sci., 6, 683 (1962)
Stacy CT, J. Appl. Polym. Sci., 32, 3959 (1986)
Park LS, Seo KH, Chang JG, Kwon YH, Han SK, Cha IH, Polym.(Korea), 13(10), 866 (1989)

[Referenced By]

[1] Margolis JM, "Engineering Thermoplastics," Marcel Dekker (1985)

[2] Hill HW, Brady DG, Chem. Tech., 49, 33 (1977)

[3] Brady DG, J. Appl. Polym. Sci., 20, 2541 (1976)

[4] Short JN, Hill HW, Chem. Tech., 2, 481 (1972)

[5] Sandler SR, Wolf Karo, "Polymer Syntheses," 3, 81, Academic Press (1980)

[6] Encyclopedia of Chemical Technology, 3rd ed., 18, 793 (1982)

[7] Lovell PA, Still RH, Makromol. Chem., 188, 111 (1987)

[8] Edmonds JT, Hill HW, U.S. Patent, 3,354,129 (1967)

[9] Edmonds JT, Hill HW, U.S. Patent, 3,524,835 (1970)

[10] Fahey DR, Ash CE, Macromolecules, 24, 4242 (1991)

[11] Tsuchida E, Macromolecules, 23, 930 (1990)

[12] Solomon OF, Ciuta IZ, J. Appl. Polym. Sci., 6, 683 (1962)

[13] Stacy CT, J. Appl. Polym. Sci., 32, 3959 (1986)

[14] Park LS, Seo KH, Chang JG, Kwon YH, Han SK, Cha IH, Polym.(Korea), 13(10), 866 (1989)