Polyacrylonitrile과 Polyurethane Ionomer 및 Nonionomer Blend

오영세; 이영민; 김병규

Polymer(Korea), Vol.16, No.6, 715-720, November, 1992

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Polyacrylonitrile과 Polyurethane Ionomer 및 Nonionomer Blend

Polyacrylonitrile Blends with Polyurethane Ionomers and Nonionomers

오영세, 이영민, 김병규

초록

폴리아크릴로니트릴(PAN)과 폴리우레탄(PU) ionomer 및 nonionomer와의 용액(DMF) blend를 제조하였다. PU anionomer(PUAn) 및 PU nonionomer(PUNo) blend에서는 입자분산형의 심한 상분리를 보인 반면, PU cationomer(PUCa) blend는 균일한 morphology를 보였다. PUCa blend에서 PU 및 PAN의 tan δ peak는 각각 저온 및 고온 쪽으로 이동하였으며, 인장강도는 additivity rule에 대하여 상당한 positive deviation을 보였으며, 특히 70/30(PAN/PUCa by wt)에서 PAN의 강도 보다 약 2.5배 증가하였다. 이러한 상승효과는 PUCa의 양이온과 PAN의 음이온에 의한 이온짝 상호작용에 의한 깃으로 판단하였다.

Blends of polyacrylonitrile(PAN) with different types of ionic and nonionic polyurethane(PU) were prepared in N,N'-dimethylformamide. Blends of PU anionomer and nonionomer showed large phase separation with spherical domains. On the contrary, PU cationomer blends showed a homogeneous morphology. In PU cationomer blends, the tan δ peak, examined by a rheovibron, of PU and PAN moved toward lower and higher temperatures respectively. In addition, the tensile strength of PU cationomer blend increased by about 2.5 times at 70/30(PAN/PUCa by wt), which was thought to be due to the ion pair interactions between PU cations and PAN anions.

[References]

Dalven PI, Laccetti AT, Hongins LT, Gregor HP, J. Appl. Polym. Sci., 30, 1113 (1985)
Polyton DJ, Text. Prog., 8, 51 (1976)
Br. Patent, 1,472,645 (1977)
Gupta AK, Songhal RP, J. Polym. Sci. B: Polym. Phys., 21, 2243 (1981)
Nedelcheva DP, Belousova TA, Tsarevskaya IY, Kozlov PV, Polym. Sci. U.S.S.R., 28, 218 (1986)
Bajaj P, Kumar MS, Text. Res. J., 59, 192 (1980)
Japan Patent, 56-053208
Japan Patent, 55-047132
Brit. Patent, 2,082,368A (1980)
U.S. Patent, 3,542,719 (1970)
Lawton EL, Murayama T, Holland VF, Felty DC, J. Appl. Polym. Sci., 25, 187 (1980)
Srichatrapimuk VW, Cooper SL, J. Macromol. Sci.-Phys., 1315, 267 (1987)
Takahara A, Tashita J, Kajiyama T, Takayanagi M, Macknight WJ, Polymer, 26, 987 (1985)
Minami SH, Saito K, Kobunshi Kagaku, 29, 114 (1972)
Kim BK, Kim TK, J. Appl. Polym. Sci., 43, 393 (1991)
Kim TK, Kim BK, Colloid Polym. Sci., 269, 889 (1991)
Mondragon I, Nazabal J, Polym. Eng. Sci., 25, 178 (1985)
Lee YK, Jeong YT, Kim KC, Jeong HM, Kim BK, Polym. Eng. Sci., 31, 944 (1991)

[Referenced By]

[1] Dalven PI, Laccetti AT, Hongins LT, Gregor HP, J. Appl. Polym. Sci., 30, 1113 (1985)

[2] Polyton DJ, Text. Prog., 8, 51 (1976)

[3] Br. Patent, 1,472,645 (1977)

[4] Gupta AK, Songhal RP, J. Polym. Sci. B: Polym. Phys., 21, 2243 (1981)

[5] Nedelcheva DP, Belousova TA, Tsarevskaya IY, Kozlov PV, Polym. Sci. U.S.S.R., 28, 218 (1986)

[6] Bajaj P, Kumar MS, Text. Res. J., 59, 192 (1980)

[7] Japan Patent, 56-053208

[8] Japan Patent, 55-047132

[9] Brit. Patent, 2,082,368A (1980)

[10] U.S. Patent, 3,542,719 (1970)

[11] Lawton EL, Murayama T, Holland VF, Felty DC, J. Appl. Polym. Sci., 25, 187 (1980)

[12] Srichatrapimuk VW, Cooper SL, J. Macromol. Sci.-Phys., 1315, 267 (1987)

[13] Takahara A, Tashita J, Kajiyama T, Takayanagi M, Macknight WJ, Polymer, 26, 987 (1985)

[14] Minami SH, Saito K, Kobunshi Kagaku, 29, 114 (1972)

[15] Kim BK, Kim TK, J. Appl. Polym. Sci., 43, 393 (1991)

[16] Kim TK, Kim BK, Colloid Polym. Sci., 269, 889 (1991)

[17] Mondragon I, Nazabal J, Polym. Eng. Sci., 25, 178 (1985)

[18] Lee YK, Jeong YT, Kim KC, Jeong HM, Kim BK, Polym. Eng. Sci., 31, 944 (1991)