Chloroprene 고무개질 에폭시화 천연고무; 1.가류거동, 동적, 굴곡/오존 균열저항특성

김인환; 이수민; 김상준; 이영민; 박찬영; 김병규

Polymer(Korea), Vol.17, No.1, 8-14, January, 1993

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Chloroprene 고무개질 에폭시화 천연고무; 1.가류거동, 동적, 굴곡/오존 균열저항특성

Chloroprene Rubber Modified Epoxidized Natural Rubber; 1.Cure Behavior, Dynamic, Flex/Ozone Crack Resistance Properties

김인환, 이수민, 김상준, 이영민, 박찬영, 김병규

초록

Master batch법으로 ENR(epoxidized natural rubber)/CR(chloroprene rubber) 블렌드를 제조, 이들의 점성 및 가류특성, resilience, 굴곡저항 및 내오존 특성들을 검토하였다. 동적특성 측정(rheovibron)으로부터 ENR/CR 블렌드는 단일 tan δ peak를 나타냄을 확인하였고, peak의 위치는 CR의 함량증가와 더불어 저온쪽으로 이동함을 볼 수 있었다. 아울러 ENR의 내오존성은 소량의 CR (10%) 첨가로 크게 개선되었다.

The ENR(epoxidized natural rubber) blends with CR(chloroprene rubber) were prepared by master batch process. Viscosity, core characteristics, resilience, flex and ozone crack resistance were subsquently determined. Dynamic measurement(rheovibron) showed a single tan δ peak for the blend, and the peak monotonically moved toward the lower temperature with the increasing content of CR. It was also found that the ozone crack resistance was significantly improved upon blending a small amount(10%) of CR.

[References]

Davis CKL, Wolfe SV, Gelling IR, Thomas AG, Polymer, 24, 107 (1983)
Baker CSL, Rubber World, pp. 24-32, September (1990)
"Natural Rubber Science and Engineering," A.D. Roberts, ed., Oxford University Press, Oxford (1988)
Han CD, "Multiphase Flow in Polymer Processing," Academic Press, New York (1981)
The Vanderbilt Rubber Handbook, Thirteenth Ed., R.T. Vanderbilt, Norwalk (1990)
Miles IS, Zurek A, Polym. Eng. Sci., 28, 796 (1988)
Lee YK, Jeong YT, Kim KC, Jeong HM, Kim BK, Polym. Eng. Sci., 31, 944 (1991)
Gardiner JB, Rubber Chem. Technol., 43, 370 (1970)
Loadman MJ, Kinker AJ, Rubber Chem. Technol., 62, 234 (1989)
Birley AW, Haworth B, Batchelor J, "Physics of Plastics," Hanser Publisher, Munich (1991)
Shen MC, Eisenberg A, Rubber Chem. Technol., 43, 95 (1970)
Roller MB, Gillham JK, J. Appl. Polym. Sci., 16, 3105 (1972)
Kim BK, Park SY, Park SJ, Eur. Polym. J., 27(4-5), 349 (1991)
"Thermoplastic Elastomers from Rubber-Plastic Blends," S.K. De and A. Bhowmick eds., Ellis Howard, New York (1990)
Keskkula H, Turley SG, Boyer RF, J. Appl. Polym. Sci., 15, 351 (1971)
Bauer RF, Dudley EA, Rubber Chem. Technol., 50, 35 (1977)
Dannis ML, J. Appl. Polym. Sci., 7, 231 (1963)

[Referenced By]

[1] Davis CKL, Wolfe SV, Gelling IR, Thomas AG, Polymer, 24, 107 (1983)

[2] Baker CSL, Rubber World, pp. 24-32, September (1990)

[3] "Natural Rubber Science and Engineering," A.D. Roberts, ed., Oxford University Press, Oxford (1988)

[4] Han CD, "Multiphase Flow in Polymer Processing," Academic Press, New York (1981)

[5] The Vanderbilt Rubber Handbook, Thirteenth Ed., R.T. Vanderbilt, Norwalk (1990)

[6] Miles IS, Zurek A, Polym. Eng. Sci., 28, 796 (1988)

[7] Lee YK, Jeong YT, Kim KC, Jeong HM, Kim BK, Polym. Eng. Sci., 31, 944 (1991)

[8] Gardiner JB, Rubber Chem. Technol., 43, 370 (1970)

[9] Loadman MJ, Kinker AJ, Rubber Chem. Technol., 62, 234 (1989)

[10] Birley AW, Haworth B, Batchelor J, "Physics of Plastics," Hanser Publisher, Munich (1991)

[11] Shen MC, Eisenberg A, Rubber Chem. Technol., 43, 95 (1970)

[12] Roller MB, Gillham JK, J. Appl. Polym. Sci., 16, 3105 (1972)

[13] Kim BK, Park SY, Park SJ, Eur. Polym. J., 27(4-5), 349 (1991)

[14] "Thermoplastic Elastomers from Rubber-Plastic Blends," S.K. De and A. Bhowmick eds., Ellis Howard, New York (1990)

[15] Keskkula H, Turley SG, Boyer RF, J. Appl. Polym. Sci., 15, 351 (1971)

[16] Bauer RF, Dudley EA, Rubber Chem. Technol., 50, 35 (1977)

[17] Dannis ML, J. Appl. Polym. Sci., 7, 231 (1963)