Cellulose-Acrylamidoxime 공중합체의 합성과 전기 전도성에 관한 연구

송해영; 박정기; 백중현; 김형년

Polymer(Korea), Vol.17, No.1, 32-38, January, 1993

Export Citation

Cellulose-Acrylamidoxime 공중합체의 합성과 전기 전도성에 관한 연구

A Study on the Synthesis and Electrical Properties of Cellulose-Acrylamidoxime Copolymer

송해영, 박정기, 백중현, 김형년

초록

전도성 셀룰로오스-아크릴아미드옥심 착물을 합성하여 착물의 형성 및 전기전도성을 조사하였다. Cu_xS를 도입한 필름의 전기전도도는 반도체 영역임을 알았으며, Cu_xS-cell-AA의 전기전도도는 Cu_xS-cell-AN 착물보다 높게 나타났다. DSC 분석 결과, Cu_xS-cell-AA가 Cu_xS-cell-AN보다 T_m값이 18℃정도 낮게 나타났으며, 착물의 표면 구조는 전자 현미경 사진으로 관찰하였는데 착물이 형성됨에 따라 더욱 조밀해진 것으로 보아 공중합체에 Cu_xS가 도입되었음을 확인할 수 있었다.

Conducting cellulose-acrylamidoxime complex was synthesized, then their complex formation and electrical conductivity were examined. Electrical conductivity of Cu_xS complex films is in the range of semiconductors. The electrical conductivity of Cu_xS-cell-AA complex is higher than that of Cu_xS-cell-AN complex. In the results of DSC, the melting temperature of Cu_xS-cell-AA complex was 18℃ lower than that of CCu_xS-cell-AN complex. The morphology of complex was also investigated by SEM. It could he confirmed that Cu_xS has been introduced into cell-AN and cell-AA from the change of surface structure, which was more compact with increasing the degree of complex formation.

[References]

Tomoble S, Gomibuchi R, Takashi K, U.S. Patent, 4,378,226 (1983)
Kang EY, Lee SG, Im SS, Polym.(Korea), 10(2), 165 (1986)
Im SS, Kang EY, Kim JW, Korea Soc. Text. Eng. Chem., 22, 48 (1985)
Kang EY, Im SS, Polym.(Korea), 10(4), 354 (1986)
Kang EY, Chungand EJ, Im SS, J. Appl. Polym. Sci., 33, 317 (1987)
Svensk PB, papperstidn, 60, 88 (1957)
Willard JJ, Pacsu E, J. Am. Chem. Soc., 82, 4347 (1960)
McMillan OJ, Decosas KM, Cooper AS, Hamalainen C, Murphy AL, Pollard EF, Am. Dyestuff Rept., 49, 839 (1960)
Hebeish A, El-Kantouch A, Rafie MH, J. Appl. Polym. Sci., 15, 11 (1971)
Compton J, Martin WH, Gargarine DM, Text. Res. J., 40, 813 (1970)
Hamaya J, Yamada S, J. Appl. Polym. Sci., 22, 875 (1978)
Sakane K, Sugasaka K, Water Sci. Jpn., 36, 101 (1982)
Song HY, Hwang TS, Kim DC, Son WG, Park JH, Park JS, Park JK, Polym.(Korea), 16(1), 1 (1992)

[Referenced By]

[1] Tomoble S, Gomibuchi R, Takashi K, U.S. Patent, 4,378,226 (1983)

[2] Kang EY, Lee SG, Im SS, Polym.(Korea), 10(2), 165 (1986)

[3] Im SS, Kang EY, Kim JW, Korea Soc. Text. Eng. Chem., 22, 48 (1985)

[4] Kang EY, Im SS, Polym.(Korea), 10(4), 354 (1986)

[5] Kang EY, Chungand EJ, Im SS, J. Appl. Polym. Sci., 33, 317 (1987)

[6] Svensk PB, papperstidn, 60, 88 (1957)

[7] Willard JJ, Pacsu E, J. Am. Chem. Soc., 82, 4347 (1960)

[8] McMillan OJ, Decosas KM, Cooper AS, Hamalainen C, Murphy AL, Pollard EF, Am. Dyestuff Rept., 49, 839 (1960)

[9] Hebeish A, El-Kantouch A, Rafie MH, J. Appl. Polym. Sci., 15, 11 (1971)

[10] Compton J, Martin WH, Gargarine DM, Text. Res. J., 40, 813 (1970)

[11] Hamaya J, Yamada S, J. Appl. Polym. Sci., 22, 875 (1978)

[12] Sakane K, Sugasaka K, Water Sci. Jpn., 36, 101 (1982)

[13] Song HY, Hwang TS, Kim DC, Son WG, Park JH, Park JS, Park JK, Polym.(Korea), 16(1), 1 (1992)