The known solvent dependence of (1)J(C-c, H-f) and (2)J(C-1, H-f) couplings in acetaldehyde is studied from a theoretical viewpoint based on the density functional theory approach where the dielectric solvent effect is taken into account with the polarizable continuum model. The four terms of scalar couplings, Fermi contact, paramagnetic spin orbital, diamagnetic spin orbital and spin dipolar, are calculated but the solvent effect analysis is restricted to the first term since for both couplings it is by far the dominant contribution. Experimental trends of Delta(1)J(C-c, H-f) and Delta(2)J(C-1, H-f) Vs epsilon (the solvent dielectric constant) are correctly reproduced although they are somewhat underestimated. Specific interactions between solute and solvent molecules are studied for dimethylsulfoxide, DMSO, solutions considering two different one-to-one molecular complexes between acetaldehyde and DMSO. They are determined by interactions of type C=O---H-C and S=O---H-C, and the effects of such interactions on (1)J(C-c, H-f) and (2)J(C-1, H-f) couplings are analyzed. Even though only in a semiquantitative way, it is shown that the effect of such interactions on the solvent effects, of Delta(1)J(C-c, H-f) and Delta(2)J(C-1, H-f), tend to improve the agreement between calculated and experimental values. These results seem to indicate that a continuum dielectric model has not enough flexibility for describing quantitatively solvent effects on spin-spin couplings. Apparently, even for relatively weak hydrogen bonding, the contribution from "direct" interactions is of the same order of magnitude as the "dielectric" effect.