The structural and electronic transport properties of self-assembled ZnO nanoparticles in polystyrene-acrylic acid, [PS](m)/[PAA](n), diblock copolymer on p-type (100)Si substrates are reported for the first time. Four different block repeat unit ratios (m/n) of 159/63, 139/17,106/17, and 106/4, were examined in order to correlate the physical parameters (size, density) of the nanoparticles with the copolymer block lengths in and n. We established that the self-assembled ZnO nanoparticle average size increased linearly with minority block length it.. while the average density decreased exponentially with majority block length m. Average size varied from 20 nm to 250 nm and average density from 3.5 x 10(7) cm(-2) to 1 x 10(10) cm(-2), depending on copolymer parameters. X-ray diffraction studies showed the particles to have a wurtzite crystal structure with the (100) being the dominant orientation. Room temperature current-voltage characteristics measured for an Al/ZnO-nanocomposite/Si structure exhibited rectifying junction properties and indicated the formation of Al/ZnO-nanocomposite Schottky type junction with a barrier height of 0.7 V. (c) 2006 Elsevier Ltd. All rights reserved.