화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.13, No.6, 879-894, November, 2007
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Electrorheological Properties of Polypyrrole and its Composite ER Fluids
Do-Heyoung Kim, and Young Dae Kim†
  • Faculty of Applied Chemical Engineering, Chonnam National University, Kwangju 500-757, Korea
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Electrorheological (ER) fluids are suspensions of polarizable nonconducting or semiconducting particles in a nonconducting continuous phase of low relative polarizability. In the absence of an electric field, they have the properties of suspensions of neutral solid particles. Upon the application of an electric field, an organized structure of particles is formed and the ER fluids exhibit a remarkable change in rheological properties, including a drastic increase in apparent viscosity as well as yield stress. Various mechanisms have been proposed to explain the ER behavior to understand the ER behaviors and design effective ER fluids. Polypyrrole (PPy) is one of the most promising semiconducting polymers because it has higher conductivity and environmental stability than many other semiconducting polymers. PPy and its composites have been extensively used as ER materials and their ER fluids showed promising ER responses. ER properties of PPy based ER fluids (PPy, PPy copolymer, PPy coated particles, and PPy nanocomposites, etc.) and the ER behaviors of PPy based ER fluids such as shear, yield, and transient stress behavior and additive effect are reviewed.
Keywords:electrorheological fluid;electrorheology;semiconducting polymer;polypyrrole;yield stress;semiconducting polymer composite
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