Synthesis of Acryl Phosphate Antistatic Agent and Its Effect on the Antistatic, Thermal and Mechanical Properties of PMMA

Eu Soo Park; Eun-Bum Cho; Dukjoon Kim

Macromolecular Research, Vol.15, No.7, 617-622, December, 2007

Eu Soo Park, Eun-Bum Cho, and Dukjoon Kim^†

Department of Chemical Engineering, Polymer Technology Institute, Sungkyunkwan University, Suwon 440-746, Korea

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A simple and economic antistatic agent, (2-methacryloyloxyethyl)acid phosphate (acryl phosphate), was synthesized via the reaction of 2-hydroxyethyl methacrylate with phosphorus pentoxide. The acryl phosphate antistatic agent, synthesized in this study, was introduced into poly(methyl methacrylate) (PMMA) resin via copolymerization with MMA. This antistatic agent provides the PMMA matrix with excellent antistatic properties, including surface resistance and electric charge. A comparison of the present antistatic agent with other commercial agents demonstrated the excellence of not only its electrical, but also its thermal and mechanical properties.

Keywords:acryl phosphate;(2-methacryloyloxyethyl)acid phosphate;antistatic agent;poly(methyl methacrylate)

[References]

Gonsalves VE, Dongeren B, Text. Res. J., 24, 1 (1954)
Hersh SP, Sharman EP, Text. Res. J., 24, 426 (1954)
Cunnigham RG, Montgomery DJ, Text. Res. J., 18, 971 (1958)
Ballow JW, Text. Res. J., 24, 146 (1954)
Holmes FH, Heap SA, J. Soc. Dyers Color, 83, 12 (1967)
Henshall AE, J. Soc. Dyers Color, 76, 525 (1960)
Marumo H, Takai M, Saito M, Kogyo Kogaku Zasshi, 72, 940 (1969)
Wilson N, Text. Inst. 1nd., 10, 235 (1972)
Mizutani T, Mitani K, Ieda M, Jpn. J. Appl. Phys. Part 1, 22, 677 (1983)
Lewis DM, Text. Res. J., 54, 279 (1984)
Jeong HM, Ahn YT, Macromol. Res., 13(2), 102 (2005)
Lee KC, Lee SY, Macromol. Res., 15(3), 244 (2007)
Friedman LA, Et AL, USP 4452709 (1984)
Marshall RM, Et AL, USP 3814627 (1974)
Park HS, Kim YG, Kim JT, Bea JS, Choi HC, Polym.(Korea), 14(2), 153 (1990)
Park HS, Kim YG, Kim JT, Bea JS, Choi HC, Polym.(Korea), 14(3), 211 (1990)
Park HS, Park DW, Kim WJ, HWAHAK KONGHAK, 28(4), 403 (1990)
Harper KA, Casimir DJ, Kinnersley HW, J. Electroanal. Chem., 9, 477 (1965)

[Referenced By]

[Related Articles]

[1] Gonsalves VE, Dongeren B, Text. Res. J., 24, 1 (1954)

[2] Hersh SP, Sharman EP, Text. Res. J., 24, 426 (1954)

[3] Cunnigham RG, Montgomery DJ, Text. Res. J., 18, 971 (1958)

[4] Ballow JW, Text. Res. J., 24, 146 (1954)

[5] Holmes FH, Heap SA, J. Soc. Dyers Color, 83, 12 (1967)

[6] Henshall AE, J. Soc. Dyers Color, 76, 525 (1960)

[7] Marumo H, Takai M, Saito M, Kogyo Kogaku Zasshi, 72, 940 (1969)

[8] Wilson N, Text. Inst. 1nd., 10, 235 (1972)

[9] Mizutani T, Mitani K, Ieda M, Jpn. J. Appl. Phys. Part 1, 22, 677 (1983)

[10] Lewis DM, Text. Res. J., 54, 279 (1984)

[11] Jeong HM, Ahn YT, Macromol. Res., 13(2), 102 (2005)

[12] Lee KC, Lee SY, Macromol. Res., 15(3), 244 (2007)

[13] Friedman LA, Et AL, USP 4452709 (1984)

[14] Marshall RM, Et AL, USP 3814627 (1974)

[15] Park HS, Kim YG, Kim JT, Bea JS, Choi HC, Polym.(Korea), 14(2), 153 (1990)

[16] Park HS, Kim YG, Kim JT, Bea JS, Choi HC, Polym.(Korea), 14(3), 211 (1990)

[17] Park HS, Park DW, Kim WJ, HWAHAK KONGHAK, 28(4), 403 (1990)

[18] Harper KA, Casimir DJ, Kinnersley HW, J. Electroanal. Chem., 9, 477 (1965)