고성능 에폭시 수지의 간인성 향상 ; Ⅱ. 개질 에폭시 수지의 형태학적 고찰

정호순; 장정식; 심정섭

Polymer(Korea), Vol.17, No.5, 513-520, September, 1993

Toughness Improvement of High Performance Epoxy Resin : Ⅱ. Morphology Study of Modified Epoxy Resin

Modified polyetherimide was applied for the improvement of the fracture toughness and mechanical property of EPON HPT 1071 recently developed by Shell Chemical Company. In HPT 1071/DDS/mPEI system, the number and size of dispersed phase within cured epoxy resin were gradually decreased with the increase of the treatment time of polyetherimide. As the content of modified polyetherimide was increased up to 10 wt%, the mechanical property of cured epoxy resin was significantly increased compared with that of the unmodified polyetherimide system. The relationship between the morphology and the mechanical properties of modified epoxy resin was also discussed.

[References]

Bucknall CB, "Toughened Plastics," London, Applied Science (1977)
Kunz SC, Beaunont PW, J. Mater. Sci., 16, 1431 (1981)
McGray FJ, Proc. Soc. London A, 319, 59 (1970)
Yee AF, Pearson RA, General Electric Co. NASA Contractor Report, 3718 (1983)
Kuns-Douglass SC, Beaumont PWR, Ashby MF, J. Mater. Sci., 15, 1109 (1980)
Bucknall CB, Yoshi T, Br. Polym. J., 10, 53 (1978)
Manzione LT, Gillham JK, J. Appl. Polym. Sci., 26, 889 (1981)
Manzione LT, Gillham JK, J. Appl. Polym. Sci., 26, 907 (1981)
Kinloch AJ, Shaw SJ, Tod DA, Hunston DL, Polymer, 24, 1341 (1983)
Kinloch AJ, Shaw SJ, Tod DA, Hunston DL, Polymer, 24, 1355 (1983)
Siebert AR, Riew CK, Paper Presented at the 161st ACS Meeting, Org. Coat. Plast. Div., Los Angeles, Cal. (1971)
Rowe EH, Siebert AR, Drake RS, Modern. Plast., 47, 110 (1970)
Meeks SC, Polymer, 15, 675 (1984)
Riew CK, Rowe EH, Siebert AR, Toughness and Brittleness of Plastics, ACS Adv., in Chem. Ser., 154: 326 (1976)
Ting RY, "Epoxy Resins," C.A. May., Ed., Marcel Dekker, Inc., p. 551-651 (1988)
Riew CK, Rubber Chem. Technol., 54, 374 (1981)
Sultan TN, McGarry FJ, Polym. Eng. Sci., 13, 29 (1973)
Romanchik WA, Sohn JFG, Am. Chem. Soc. Symp. Ser., 221, 85 (1982)
Kinloch AJ, Shaw SJ, Tod DA, Huston DL, Polymer, 24, 1341 (1985)
Okamoto A, Polym. Eng. Sci., 23, 222 (1983)
Yorkgitis EM, Eiss NS, "Epoxy Resins and Composites I," K. Dusek, Ed., Spinger-Verlag, Berlin, pp. 79-109 (1986)
Yorkgitis EM, Ph.D. Thesis, Virginia Polytechnic Inst. & State Univ., Blacksburg (1985)
Lee W, "A Study on New Tetrafunctional Epoxy Resin for Advanced Composite," Ph.D. Dissertation, Seoul National University (1991)
Browning CE, Polym. Eng. Sci., 18, 16 (1978)
McKangue EL, Reynold JD, Haskin JE, J. Appl. Polym. Sci., 22, 1643 (1978)
Apicella A, Nicolais L, Astarita G, Drioli E, Polymer, 20(9), 1143 (1979)
Bauer RS, 18th International SAMPE Technical Conference, October 7-9, pp. 510-519 (1986)
Chan LC, Gillham JK, Kinloch AJ, Shaw SJ, "Rubber-Modified Thermoset Resins," American Chemical Society, p. 261 (1984)
Henry S, Hsich Y, 34th International SAMPE Symposium May 8-11, 884 (1989)
Younhing H, Huigong W, Xiping Z, 34th International SAMPE Symposium May 8-11, 875 (1989)
Riley BL, V8/GR, MK5 Air frame composite application, in proceedings of the second international conference on fiber reinforced composites, Inst. of Mech. Eng., Publication C33/86, p. 153 (1986)
Poveromo L, "Polyimides," K.L. Mittel Ed., Plenum Press, New York & London, Vol. 2, p. 1103 (1984)
Rayhava RS, 28th National SAMPE Conference 28, 367 (1983)
Selton MS, McGrail PT, Peacock JA, Wilknson SP, Crick RA, Davies M, Almen G, 19th International SAMPE Technical Conference, 19, 700 (1987)
Shimp DA, Hudock FA, Boho WS, 18th International SAMPE Technical Conference, 18, 851 (1986)
Steiner P, Browne JM, Balin MT, McKillen JM, 18th International SAMPE Technical Conference, 18, 851 (1986)
Stenzenberger HD, Konig P, Herzog M, Romer W, Pierce S, Canning M, 32nd International SAMPE Symposium, 32, 44 (1987)
Jung HS, Jang JS, Shim JS, Polym.(Korea), 17(4), 415 (1993)
Okamoto A, Polym. Eng. Sci., 23, 222 (1983)
Yorkgitis EM, Eiss NS, "Epoxy Resins and Composites I," K. Dusek, Ed., Springer-Verlag, Berlin, pp. 79-109 (1986)
May CA, "Epoxy Resin Chemistry and Technology," Ed. C.A. May,Marcel Dekker, Inc., New York and Basel, pp. 552 (1988)
Bauer RS, The Proceedings of 34th International SAMPE Symposium, May 7-11, pp. 1385-1393 (1988)

[Referenced By]

[1] Bucknall CB, "Toughened Plastics," London, Applied Science (1977)

[2] Kunz SC, Beaunont PW, J. Mater. Sci., 16, 1431 (1981)

[3] McGray FJ, Proc. Soc. London A, 319, 59 (1970)

[4] Yee AF, Pearson RA, General Electric Co. NASA Contractor Report, 3718 (1983)

[5] Kuns-Douglass SC, Beaumont PWR, Ashby MF, J. Mater. Sci., 15, 1109 (1980)

[6] Bucknall CB, Yoshi T, Br. Polym. J., 10, 53 (1978)

[7] Manzione LT, Gillham JK, J. Appl. Polym. Sci., 26, 889 (1981)

[8] Manzione LT, Gillham JK, J. Appl. Polym. Sci., 26, 907 (1981)

[9] Kinloch AJ, Shaw SJ, Tod DA, Hunston DL, Polymer, 24, 1341 (1983)

[10] Kinloch AJ, Shaw SJ, Tod DA, Hunston DL, Polymer, 24, 1355 (1983)

[11] Siebert AR, Riew CK, Paper Presented at the 161st ACS Meeting, Org. Coat. Plast. Div., Los Angeles, Cal. (1971)

[12] Rowe EH, Siebert AR, Drake RS, Modern. Plast., 47, 110 (1970)

[13] Meeks SC, Polymer, 15, 675 (1984)

[14] Riew CK, Rowe EH, Siebert AR, Toughness and Brittleness of Plastics, ACS Adv., in Chem. Ser., 154: 326 (1976)

[15] Ting RY, "Epoxy Resins," C.A. May., Ed., Marcel Dekker, Inc., p. 551-651 (1988)

[16] Riew CK, Rubber Chem. Technol., 54, 374 (1981)

[17] Sultan TN, McGarry FJ, Polym. Eng. Sci., 13, 29 (1973)

[18] Romanchik WA, Sohn JFG, Am. Chem. Soc. Symp. Ser., 221, 85 (1982)

[19] Kinloch AJ, Shaw SJ, Tod DA, Huston DL, Polymer, 24, 1341 (1985)

[20] Okamoto A, Polym. Eng. Sci., 23, 222 (1983)

[21] Yorkgitis EM, Eiss NS, "Epoxy Resins and Composites I," K. Dusek, Ed., Spinger-Verlag, Berlin, pp. 79-109 (1986)

[22] Yorkgitis EM, Ph.D. Thesis, Virginia Polytechnic Inst. & State Univ., Blacksburg (1985)

[23] Lee W, "A Study on New Tetrafunctional Epoxy Resin for Advanced Composite," Ph.D. Dissertation, Seoul National University (1991)

[24] Browning CE, Polym. Eng. Sci., 18, 16 (1978)

[25] McKangue EL, Reynold JD, Haskin JE, J. Appl. Polym. Sci., 22, 1643 (1978)

[26] Apicella A, Nicolais L, Astarita G, Drioli E, Polymer, 20(9), 1143 (1979)

[27] Bauer RS, 18th International SAMPE Technical Conference, October 7-9, pp. 510-519 (1986)

[28] Chan LC, Gillham JK, Kinloch AJ, Shaw SJ, "Rubber-Modified Thermoset Resins," American Chemical Society, p. 261 (1984)

[29] Henry S, Hsich Y, 34th International SAMPE Symposium May 8-11, 884 (1989)

[30] Younhing H, Huigong W, Xiping Z, 34th International SAMPE Symposium May 8-11, 875 (1989)

[31] Riley BL, V8/GR, MK5 Air frame composite application, in proceedings of the second international conference on fiber reinforced composites, Inst. of Mech. Eng., Publication C33/86, p. 153 (1986)

[32] Poveromo L, "Polyimides," K.L. Mittel Ed., Plenum Press, New York & London, Vol. 2, p. 1103 (1984)

[33] Rayhava RS, 28th National SAMPE Conference 28, 367 (1983)

[34] Selton MS, McGrail PT, Peacock JA, Wilknson SP, Crick RA, Davies M, Almen G, 19th International SAMPE Technical Conference, 19, 700 (1987)

[35] Shimp DA, Hudock FA, Boho WS, 18th International SAMPE Technical Conference, 18, 851 (1986)

[36] Steiner P, Browne JM, Balin MT, McKillen JM, 18th International SAMPE Technical Conference, 18, 851 (1986)

[37] Stenzenberger HD, Konig P, Herzog M, Romer W, Pierce S, Canning M, 32nd International SAMPE Symposium, 32, 44 (1987)

[38] Jung HS, Jang JS, Shim JS, Polym.(Korea), 17(4), 415 (1993)

[39] Okamoto A, Polym. Eng. Sci., 23, 222 (1983)

[40] Yorkgitis EM, Eiss NS, "Epoxy Resins and Composites I," K. Dusek, Ed., Springer-Verlag, Berlin, pp. 79-109 (1986)

[41] May CA, "Epoxy Resin Chemistry and Technology," Ed. C.A. May,Marcel Dekker, Inc., New York and Basel, pp. 552 (1988)

[42] Bauer RS, The Proceedings of 34th International SAMPE Symposium, May 7-11, pp. 1385-1393 (1988)