화학공학소재연구정보센터
Journal of Supercritical Fluids, Vol.35, No.3, 260-264, 2005
Superior mirage effect in supercritical CO2: Experiment and model
At temperatures near T-c, supercritical CO2 is highly compressible and it follows that a small temperature gradient will create a large density gradient. We established stable density gradients by maintaining the bottom of a SC-CO2-cell cooler than its other sides. That created a large refractive index gradient that bent a laser beam through an angle that is roughly proportional to the density gradient. Such light bending causes, for example, the mirage of water on a hot road. A He-Ne laser beam traversed a 7.62 cm Iona cell and was deflected downward as much as 5.9 degrees. The magnitude of the beam deflections agreed within 3% with a model that used only fundamental geometrical optics and known PVT data, but that employed no adjustable parameters. (c) 2005 Elsevier B.V. All rights reserved.