In this study we report 3D simulation of concentration profiles in a fixed bed packed with spherical porous adsorbents using lattice Boltzmann methods (LBMs). The lattice models have been developed to investigate evolution of concentration profiles due to inter- and intra-particle mass transport in an adsorber having small tube-to-sphere diameter (d(t)/d(p)) ratios. The multi-scaling feature of LBMs permits full 3D simulation of concentration profiles both in the bed voids and within the pores of the adsorbents without using any empirical correlations or without making 1D or 2D approximations that are usually made in traditional numerical methods. The model simulation is carried out for varying packing arrangements and small to large pore diffusivities. The simulation results show significant concentration gradients for small pore diffusivities and large particle size, which must be considered in predicting breakthrough and adsorption times for a tubular adsorber having d(t)/d(p) < 10. The model predicted breakthrough curves are validated with the experimental data obtained by tomography technique in a tubular adsorber packed with zeolite particles. (c) 2007 Elsevier Ltd. All rights reserved.