화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of the Korean Industrial and Engineering Chemistry, Vol.19, No.1, 1-16, February, 2008
Export Citation
가시광 감응 산화티탄(TiO2)
Visible Light Responsive Titanium Dioxide (TiO2)
손호경1, Sherub Phuntsho1, Yousef Okour1, 조동련2, 김경석2, 이휘지2, 나숙현2, 김종범2, 3, 김종호2, 3, †
  • 1시드니공과대학교 환경공학부, Sydney, P.O. Box 123, Broadway, NSW 2007
  • 2전남대학교 응용화학공학부 촉매연구소, 광주 500-757
  • 3(주)빛과환경 환경기술연구소, 광주 500-460
Hokyong Shon1, Sherub Phuntsho1, Yousef Okour1, Dong-Lyun Cho2, Kyoung Seok Kim2, Hui-Jie Li2, Sukhyun Na2, Jong Beom Kim2, 3, and Jong-Ho Kim2, 3, †
  • 1Faculty of Engineering, University of Technology, Sydney, P.O. Box 123, Broadway, NSW 2007, Australia
  • 2School of Applied Chemical Engineering & The Research Institute for Catalysis, Chonnam National University, Gwangju 500-757, Korea
  • 3Photo & Environmental Technology Co. Ltd., Gwangju 500-460, Korea
E-mail:
초록
산화티탄은 가장 많이 연구된 반도체 산화물로 환경 정화와 에너지 생산에 응용이 크게 기대되고 있다. 공기와 물 속의 유해 유기물을 제거하고 물분해를 통한 수소 생산은 대표적인 응용 분야이다. 산화티탄의 저렴한 가격, 낮은 독성, 화학적 및 열적 안정성은 잘 알려진 장점이다. 그러나, 산화티탄의 단점은 가시광 영역에서 광촉매 활성이 낮다는 점이다. 이러한 문제점을 해결하기 위하여, 귀금속, 금속, 양이온, 음이온 도핑 방법으로 산화티탄의 표면과 전기적 구조를 변형시켜 가시광 영역에서 광촉매 활성을 높이기 위한 연구가 많이 진행되고 있다. 이번 총설에서는 산화티탄의 가시광 감응을 유도하는 방법에 대한 광범위한 정보를 정리하였다.
Titanium dioxide (TiO2) is one of the most researched semiconductor oxides that has revolutionised technologies in the field of environmental purification and energy generation. It has found extensive applications in heterogenous photocatalysis for removing organic pollutants from air and water and also in hydrogen production from photocatalytic water-splitting. Its use is popular because of its low cost, low toxicity, high chemical and thermal stability. But one of the critical limitations of TiO2 as photocatalyst is its poor response to visible light. Several attempts have been made to modify the surface and electronic structures of TiO2 to enhance its activity in the visible light region such as noble metal deposition, metal ion loading, cationic and anionic doping and sensitisation. Most of the results improved photocatalytic performance under visible light irradiation. This paper attempts to review and update some of the information on the TiO2 photocatalytic technology and its accomplishment towards visible light region.
Keywords:visible light photocatalyst;titanium dioxide;semiconductor;TiO2 modification
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