Journal of Physical Chemistry A, Vol.111, No.46, 11809-11813, 2007
Comparison of two types of dispersive kinetic approaches in relation to time-dependent Marcus theory
Two different approaches presented in recent literature for the treatment of dispersive kinetics for a first-order (H) conversion mechanism are compared from a physicochemical perspective. The author's approach is found to be successful in describing activation energy trends as a function of time that can be predicted from a simple extension of Marcus theory. Thus, the approach is considered to have a sound fundamental basis.