The effect of alkyl chain length on micelle formation in aqueous solutions of synthetic alkyloxyethyl glycosides containing an ethyl spacer with different conformations of the disaccharide headgroups was investigated. The molecular shape was systematically changed from a wedge-shaped to a rodlike geometry by changing the type of carbohydrate headgroup. The lipophilic part consists of dodecyl or tetradecyl chains. The adsorption at the liquid-air interface was investigated by surface tension measurements. The micellar phase region (L-1) was studied using small-angle neutron scattering. We have observed a strong influence of the linkage between the sugar moieties in the disaccharide headgroup and the ethyl spacer on the micellar structure: the transformation from spherical to disklike aggregates was observed for compounds with a rodlike shape, but only spherical aggregates were formed by the wedge-shaped molecules.