화학공학소재연구정보센터
Electrochimica Acta, Vol.52, No.24, 7068-7074, 2007
Evaluation of corrosion and erosion-corrosion resistances of mild steel in sulfide-containing NaCl aerated solutions
This paper reports results of potentiodynamic polarization, electrochemical impedance measurements and erosion-corrosion of mild steel in aerated sulfide containing 3.5% NaCl solutions at room temperature. The pitting corrosion behavior was studied in NaCl solution containing 0.001, 0.005 and 0.010M Na2S, using potentiodynamic polarization and electrochemical impedance spectroscopy. The erosion-corrosion resistance was evaluated after rotating the samples in sulfide polluted NaCl solution for 24h at a velocity of 300, 600 and 900ppm using a rotating disc electrode. Results showed that the presence of sulfide ions in NaCl solution resulted in a significant increase in the corrosion attack due to the local acidification caused by iron sulfide formation. The localized replacement of the protective Fe-oxide film by a non-protective iron sulfide film is responsible for the pitting and erosion-corrosion attack. The study concluded that the higher the concentration of sulfide in NaCl solution, the lower the resistance to pitting and erosion-corrosion. Moreover, increasing the solution rotating velocity affects negatively the erosion-corrosion resistance. ((c) 2007 Elsevier Ltd. All rights reserved.