This work presents a study about the efficiency of destruction of industrial waste, used in the co-incineration in rotary kilns of the cement industry, considering the principle of the chemistry equilibrium and the kinetic of the reactions. As an example, it has analysed the burn of one hazardous waste which has in its composition toluene, xylene and dicloroethane. The temperatures of the transformation and the time of the reaction to the formation of sub-products which will originate CO2, H2O and HCl, are evaluated. Thus, the formation of the pollutants in the kiln is preliminary estimated and the different forms to control the emissions is also discussed.