Journal of Colloid and Interface Science, Vol.315, No.1, 270-277, 2007
Interfacial properties of colloid-polymer mixtures
Density functional theory and a virial approach are used to calculate the surface tension and bending rigidity of the interface between demixed fluid phases for a colloid-polymer mixture. The calculated surface tension compares well with results from computers simulations and experiments. The bending rigidity obtained from both theoretical approaches is negative (approximate to -0.1k(B)T), its magnitude increases away from the critical point and it is in reasonable agreement with computer simulations. (C) 2007 Elsevier Inc. All rights reserved.
Keywords:colloid-polymer mixture;surface tension;bending rigidity;squared-gradient model;capillary wave theory