계면활성체를 이용한 분자 다층 구조의 합성

신재섭

Polymer(Korea), Vol.19, No.3, 379-384, May, 1995

Export Citation

계면활성체를 이용한 분자 다층 구조의 합성

Synthesis of Molecular Multilayer Structure with Surfactant

신재섭

초록

콜레스테롤을 갖는 계면활성제들을 합성하고 이 계면활성제들을 물 속에서 sonication하여 vesicle 용액을 형성한 다음, 이 용액을 건조하여 분자들이 규칙적으로 배열된 분자 다충 구조를 합성하였다. 이 막들을 X-ray diffractometer로 분석하여 다층 구조를 어느 정도 잘 하고 있는지를 살펴보았다. 또한 trough를 이용하여 단분자막을 형성시킨 후, 이것을 여러번 transfer하여 분자 다층 구조를 합성하였다. 이 경우에 증류수만을 사용하면 transfer가 일어나지 않으며 polystyrene-sulfonic acid potassium salt를 첨가한 수용액 위에서는 transfer가 가능하였다.

Cholesterol-containing surfactants were synthesized, and sonicated in water to form a vesicle solution. To form a molecular multilayer structure this vesicle solution was dried. Using a X-ray diffractometer the thickness of one layer and the regularity of the multilayer were measured. The monolayer was formed in a trough and the multilayer was formed by transferring the monolayer to a substrate sevearal times. In this case the monolayer could not be transferred in water, but could be transferred in water solution of polystyrenesulfonic acid potassium salt.

Keywords:multilayer;monolayer;cholesterol;vesicle

[References]

Fendler JH, Accounts Chem. Res., 13, 7 (1980)
Fendler JH, "Membrane Mimetic Chemistry," pp. 160-168, John Wiley & Sons, New York (1982)
Tunuli MS, Fendler JH, J. Am. Chem. Soc., 103, 2507 (1981)
Tricot YM, Fendler JH, J. Am. Chem. Soc., 106, 7359 (1984)
Moss RA, Shin JS, J. Chem. Soc.-Chem. Commun., 1027 (1983)
Moss RA, Bhattacharya S, Scrimin P, Swarup S, J. Am. Chem. Soc., 109, 5740 (1987)
Moss RA, Okumura Y, J. Am. Chem. Soc., 114, 1750 (1992)
Cho I, Shin JS, Polym.(Korea), 15(2), 170 (1991)
Shin JS, J. Korean Ind. Eng. Chem., 2(1), 64 (1991)
Bae DH, Kim KS, Shin JS, J. Korean Ind. Eng. Chem., 3(2), 335 (1992)
Cho I, Chung KC, Macromolecules, 17, 2935 (1984)
Cho I, Chung KC, Macromolecules, 21, 565 (1988)
Cho I, Park JG, Chem. Lett., 977 (1987)
Cho I, Kim YW, Polym. Bull., 24, 545 (1990)
Cho I, Kim SH, Shin JS, J. Korean Ind. Eng. Chem., 3(2), 273 (1992)
Lee H, Chemworld, 33, 814 (1993)
Park JW, Chemworld, 34, 111 (1994)
Lee H, Polym. Sci. Technol., 5(5), 471 (1994)
Higashi N, Kunitake T, Chem. Lett., 105 (1986)
Chi LF, Johnston RR, Ringsdorf H, Kimizuka N, Kunitake T, Thin Solid Films, 210-211, 111 (1992)
Nakashima N, Ando R, Kunitake T, Chem. Lett., 1577 (1983)

[Referenced By]

[1] Fendler JH, Accounts Chem. Res., 13, 7 (1980)

[2] Fendler JH, "Membrane Mimetic Chemistry," pp. 160-168, John Wiley & Sons, New York (1982)

[3] Tunuli MS, Fendler JH, J. Am. Chem. Soc., 103, 2507 (1981)

[4] Tricot YM, Fendler JH, J. Am. Chem. Soc., 106, 7359 (1984)

[5] Moss RA, Shin JS, J. Chem. Soc.-Chem. Commun., 1027 (1983)

[6] Moss RA, Bhattacharya S, Scrimin P, Swarup S, J. Am. Chem. Soc., 109, 5740 (1987)

[7] Moss RA, Okumura Y, J. Am. Chem. Soc., 114, 1750 (1992)

[8] Cho I, Shin JS, Polym.(Korea), 15(2), 170 (1991)

[9] Shin JS, J. Korean Ind. Eng. Chem., 2(1), 64 (1991)

[10] Bae DH, Kim KS, Shin JS, J. Korean Ind. Eng. Chem., 3(2), 335 (1992)

[11] Cho I, Chung KC, Macromolecules, 17, 2935 (1984)

[12] Cho I, Chung KC, Macromolecules, 21, 565 (1988)

[13] Cho I, Park JG, Chem. Lett., 977 (1987)

[14] Cho I, Kim YW, Polym. Bull., 24, 545 (1990)

[15] Cho I, Kim SH, Shin JS, J. Korean Ind. Eng. Chem., 3(2), 273 (1992)

[16] Lee H, Chemworld, 33, 814 (1993)

[17] Park JW, Chemworld, 34, 111 (1994)

[18] Lee H, Polym. Sci. Technol., 5(5), 471 (1994)

[19] Higashi N, Kunitake T, Chem. Lett., 105 (1986)

[20] Chi LF, Johnston RR, Ringsdorf H, Kimizuka N, Kunitake T, Thin Solid Films, 210-211, 111 (1992)

[21] Nakashima N, Ando R, Kunitake T, Chem. Lett., 1577 (1983)