SO<sub>3</sub>로 술폰화된 Polyphenylene Sulfide의 이온교환능

손원근; 문선모; 백중현; 김동철; 박정기; 송해영

Polymer(Korea), Vol.19, No.4, 433-437, July, 1995

Export Citation

SO₃로 술폰화된 Polyphenylene Sulfide의 이온교환능

Ion Exchange Capacity of Poly(Phenylene sulfide) Sulfonated with Sulfur Trioxide

손원근, 문선모, 백중현, 김동철, 박정기, 송해영

초록

Sulfonated polyphenylene sulfide (S-PPS)는 poly(phenylene) sulfide (PPS)를 액체 SO₃로 술폰화하여 합성하였으며 1140∼1280cm^-1의 영역에서 방향족 술폰산의 술폰산기에 의한 강한 흡수대에 의하여 확인되었다. 수용성 S-PPS와 불용성 S-PPS의 이온교환용량은 각각 3.231 meq/g과 2.866 meq/g이었다. 불용성 S-PPS는 경화온도가 증가할수록 이온교환용량과 술폰산기의 IR흡광도는 감소하였다. 그리고 금속이온 흡착능과 인접 페닐기간의 가교결합 형성에 관하여 논의하였다.

Sulfonated poly(phenylene sulfide) (S-PPS) was prepared by the reaction of poly(phenylene sulfide) (PPS) with sulfur trioxide. The sulfonation was confirmed by the high intensity band of the SO₃H group at 1140∼1280 cm^-1. The ion exchange capacity of soluble S-PPS and insoluble S-PPS was 3.231 meq/g and 2.866 meq/g, respectively. The ion exchange capacity and IR absorbance of SO₃H group of S-PPS were decreased as the curing temperature was increased. In addition, the adsorption of S-PPS for metal ions and the formation of crosslinkage between neighbouring phenyl rings of S-PPS were discussed.

Keywords:ion exchange capacity;sulfonated poly(phenylene sulfide)

[References]

Nagasawa F, Sato T, Masuhara Y, Japan Patent, 186179 (1951)
Nagasawa F, Sato T, Masuhara Y, Japan Patent, 186180 (1951)
Hale DK, Reichenberg D, Discuss. Faraday Soc., 7, 79 (1949)
Boyer RF, U.S. Patent, 2,500,149 (1950)
Kimura SG, Ind. Eng. Chem. Prod. Res. Dev., 10(3), 335 (1971)
Chludzinski PJ, Fickett AP, Lacanti AB, Am. Chem. Soc. Div. Polym. Chem. Polym. Polym. Prepr., 12(2), 276 (1971)
Noshay A, Robenson LM, J. Appl. Polym. Sci., 20, 1885 (1976)
Ueno J, Watanabe M, Tanaka Y, Japan Patent, 24998 (1965)
Kibler CJ, Lappin GR, U.S. Patent, 3,734,874 (1973)
Salle R, Sillion B, FR Patent, 2212356 (1974)
Montoneri E, J. Appl. Electrochem., 18, 280 (1988)
Montoneri E, J. Polym. Sci. A: Polym. Chem., 27, 3043 (1989)
Giuffre L, Modica G, ho BM, Tempesti E, Int. J. Hydrog. Energy, 9, 179 (1984)
Schoch KF, Chance JF, Pfeiffer KE, Macromolecules, 18, 2389 (1985)
Hruszka P, Jurga J, Brycki B, Polymer, 33, 248 (1992)
Brady DG, J. Appl. Polym. Sci., 36, 231 (1981)
Lopez LC, Wilkes GL, J. Macromol. Sci.-Phys., C29(1), 83 (1989)
Lee KS, "Inorganic Quantitative Analytical Chemistry," p. 269, Dong Myong Sa, Seoul (1958)
Park KC, "Quantitative Analytical Chemistry," 5th Ed., p. 231-453, Tam Ku Dang, Seoul (1976)
Song HY, Miyatake K, Yamamoto K, Tsuchida E, J. Polym. Adv. Technol., 5, 309 (1994)
Kim DW, Kim KS, Lee NK, J. Korean Chem. Soc., 29(3), 168 (1985)
Khym JX, "Analytical Ion-Exchange Procedures in Chemistry and Biology," p. 11 (1974)

[Referenced By]

[1] Nagasawa F, Sato T, Masuhara Y, Japan Patent, 186179 (1951)

[2] Nagasawa F, Sato T, Masuhara Y, Japan Patent, 186180 (1951)

[3] Hale DK, Reichenberg D, Discuss. Faraday Soc., 7, 79 (1949)

[4] Boyer RF, U.S. Patent, 2,500,149 (1950)

[5] Kimura SG, Ind. Eng. Chem. Prod. Res. Dev., 10(3), 335 (1971)

[6] Chludzinski PJ, Fickett AP, Lacanti AB, Am. Chem. Soc. Div. Polym. Chem. Polym. Polym. Prepr., 12(2), 276 (1971)

[7] Noshay A, Robenson LM, J. Appl. Polym. Sci., 20, 1885 (1976)

[8] Ueno J, Watanabe M, Tanaka Y, Japan Patent, 24998 (1965)

[9] Kibler CJ, Lappin GR, U.S. Patent, 3,734,874 (1973)

[10] Salle R, Sillion B, FR Patent, 2212356 (1974)

[11] Montoneri E, J. Appl. Electrochem., 18, 280 (1988)

[12] Montoneri E, J. Polym. Sci. A: Polym. Chem., 27, 3043 (1989)

[13] Giuffre L, Modica G, ho BM, Tempesti E, Int. J. Hydrog. Energy, 9, 179 (1984)

[14] Schoch KF, Chance JF, Pfeiffer KE, Macromolecules, 18, 2389 (1985)

[15] Hruszka P, Jurga J, Brycki B, Polymer, 33, 248 (1992)

[16] Brady DG, J. Appl. Polym. Sci., 36, 231 (1981)

[17] Lopez LC, Wilkes GL, J. Macromol. Sci.-Phys., C29(1), 83 (1989)

[18] Lee KS, "Inorganic Quantitative Analytical Chemistry," p. 269, Dong Myong Sa, Seoul (1958)

[19] Park KC, "Quantitative Analytical Chemistry," 5th Ed., p. 231-453, Tam Ku Dang, Seoul (1976)

[20] Song HY, Miyatake K, Yamamoto K, Tsuchida E, J. Polym. Adv. Technol., 5, 309 (1994)

[21] Kim DW, Kim KS, Lee NK, J. Korean Chem. Soc., 29(3), 168 (1985)

[22] Khym JX, "Analytical Ion-Exchange Procedures in Chemistry and Biology," p. 11 (1974)