Small clusters of rare-gas atoms are ideal test cases for studying how quantum delocalization affects both the thermodynamics and the structure of molecular scale systems. In this paper, we use a variational quantum hydrodynamic approach to examine the structure and dynamics of (Ne), clusters, with n up to 100 atoms, at both T = 0 K and for temperatures spanning the solid-to-liquid transition in bulk Ne. Finite temperature contributions are introduced to the grand potential in the form of an "entropy" potential. One surprising result is the prediction of a negative heat capacity for very small clusters that we attribute to the nonadditive nature of the total free-energy for very small systems.