Journal of the American Chemical Society, Vol.129, No.29, 8944-8944, 2007
Bifunctional [c2]daisy-chains and their incorporation into mechanically interlocked polymers
A strategy for the formation of mechanically interlocked polymers is presented. Ring-closing olefin metathesis has been shown to provide a very high yielding route to [c2]daisy-chains suitably functionalized to allow their one-step conversion to bisolefins which can be used as monomers in ADMET polymerizations to afford mechanically interlocked polymers. Metathesis, in two different guises is making a hitherto unreachable goal in synthesis a reality.