Journal of the American Chemical Society, Vol.129, No.40, 12106-12106, 2007
Heterobivalent library expansion by "living radical" processes: Thiocarbonyl addition/elimination, and nitroxide-based reactions with fluorous deconvolution
Degenerate radical addition fragmentation and nitroxide fragmentation reactions are applied to the expansion of heterobivalent libraries without contamination from homobivalent species. Deconvolution by means of a fluorous tagging process is described.