폴리우레탄/폴리카보네이트 블렌드의 상용성에 대한 연구

안태완; 정순욱; 정한모

Polymer(Korea), Vol.19, No.5, 606-614, September, 1995

Export Citation

폴리우레탄/폴리카보네이트 블렌드의 상용성에 대한 연구

Study on the Miscibility of Polyurethane/Polycarbonate Binary Blends

안태완, 정순욱, 정한모

초록

4,4'-Diphenylmethane diisocyanate, 1,4-butanediol, 및 poly(ethylene adipate) biol 또는 poly(butylene adipate) diol (M_n=2000)을 사용하고, N,N-dimethylformamide를 용매로 하여 2단계 중합법에 의해 hard segment 함량이 24∼100wt%인 폴리우레탄(PU)을 합성하였다. 합성된 PU를 용액 블렌드법으로 bisphenol-A polycarbonate(PC)와 블렌드하여 그 상용 거동을 고찰하였다. PU/PC 블렌드물은 시차열량분석 시의 용융 온도 잊 가열 시간에 따라 단일상 또는 두 개의 상을 가지는 거동을 나타내었다. 이와 같은 거동의 이유는 PU와 PC간에 교환 반응이 일어나기 때문으로 판단되었고, 그 거동을 열분석 방법에 의해 관찰하였다.

Polyurethane (PU) was synthesized from 4,4'-diphenylmethane diisocyanate, 1,4-butanediol, and poly(ethylene adipate) or poly(butylene adipate) diol (M_n= 2000) as a soft segment by prepolymer method in N,N-dimethylformamide. Hard segment content of PU was varied from 24 to 100 wt%. The synthesized PU was blended with bisphenol-A polycarbon-ate (PC) from a solution by casting method. PU/PC blends exhibited either two or single phase behavior depending on temperature and duration time of annealing by a differential scanning calorimeter. Such a behavior was attributed to the transreaction between PU and PC, and was studied further by thermal analysis methods.

Keywords:polyurethane;polycarbonate;miscibility;transreaction

[References]

Brydson JA, "Plastics Materials," 5ed., p. 530, Butterworths, London (1989)
Richardson TL, "Industrial Plastics," p. 166, Delmar, New York (1989)
Honma S, Kino Zairyo, Jan., 40 (1988)
Takashi I, Kino Zairyo, Jan., 5 (1988)
Bonk HW, "Reaction Polymers," W.F. Gum, W. Riese. K, and H. Ulrich, eds., p. 279, Hanser, New York (1992)
Goyert W, U.S. Patent, 4,342,847 (1982)
Skochdopole RE, U.S. Patent, 4,912,177 (1990)
Goldblum KB, U.S. Patent, 3,431,224 (1969)
Schmelzer HG, U.S. Patent, 4,350,799 (1982)
Boutni OM, Eur. Patent, 265,790 (1983)
Eric C, Rubber World, 199(6), 30 (1989)
Koberstein JT, Gancarz I, J. Polym. Sci. B: Polym. Phys., 24, 2487 (1986)
Cruz CA, Paul DR, Barlow JW, J. Appl. Polym. Sci., 24, 2101 (1979)
Cruz CA, Barlow JW, Paul DR, Macromolecules, 12, 726 (1979)
Wahrmund DC, Paul DR, Barlow JW, J. Appl. Polym. Sci., 22, 2155 (1978)
Cruz CA, paul DR, Barlow JW, J. Appl. Polym. Sci., 23, 589 (1979)
Snell FD, Ettre LS, "Encyclopedia of Industrial Chemical Analysis," vol. 19, p. 285, Interscience, New York (1979)
Brunnette CM, Hsu SL, MacKnight WJ, Macromolecules, 15, 71 (1982)
Koberstein JT, Galambos AF, Macromolecules, 25, 5618 (1992)
Li Y, Gao T, Liu J, Linliu K, Desper CR, Chu B, Macromolecules, 25, 7365 (1993)
Koberstein JT, Gancarz I, J. Polym. Sci. B: Polym. Phys., 24, 2487 (1986)

[Referenced By]

[1] Brydson JA, "Plastics Materials," 5ed., p. 530, Butterworths, London (1989)

[2] Richardson TL, "Industrial Plastics," p. 166, Delmar, New York (1989)

[3] Honma S, Kino Zairyo, Jan., 40 (1988)

[4] Takashi I, Kino Zairyo, Jan., 5 (1988)

[5] Bonk HW, "Reaction Polymers," W.F. Gum, W. Riese. K, and H. Ulrich, eds., p. 279, Hanser, New York (1992)

[6] Goyert W, U.S. Patent, 4,342,847 (1982)

[7] Skochdopole RE, U.S. Patent, 4,912,177 (1990)

[8] Goldblum KB, U.S. Patent, 3,431,224 (1969)

[9] Schmelzer HG, U.S. Patent, 4,350,799 (1982)

[10] Boutni OM, Eur. Patent, 265,790 (1983)

[11] Eric C, Rubber World, 199(6), 30 (1989)

[12] Koberstein JT, Gancarz I, J. Polym. Sci. B: Polym. Phys., 24, 2487 (1986)

[13] Cruz CA, Paul DR, Barlow JW, J. Appl. Polym. Sci., 24, 2101 (1979)

[14] Cruz CA, Barlow JW, Paul DR, Macromolecules, 12, 726 (1979)

[15] Wahrmund DC, Paul DR, Barlow JW, J. Appl. Polym. Sci., 22, 2155 (1978)

[16] Cruz CA, paul DR, Barlow JW, J. Appl. Polym. Sci., 23, 589 (1979)

[17] Snell FD, Ettre LS, "Encyclopedia of Industrial Chemical Analysis," vol. 19, p. 285, Interscience, New York (1979)

[18] Brunnette CM, Hsu SL, MacKnight WJ, Macromolecules, 15, 71 (1982)

[19] Koberstein JT, Galambos AF, Macromolecules, 25, 5618 (1992)

[20] Li Y, Gao T, Liu J, Linliu K, Desper CR, Chu B, Macromolecules, 25, 7365 (1993)

[21] Koberstein JT, Gancarz I, J. Polym. Sci. B: Polym. Phys., 24, 2487 (1986)