화학공학소재연구정보센터
Thin Solid Films, Vol.515, No.18, 7080-7085, 2007
Two-dimensional versus three-dimensional post-deposition grain growth in epitaxial oxide thin films Influence of the substrate surface roughness
Epitaxial thin films made of nanosized yttria-stabilized zirconia islands deposited on (0001) sapphire substrates are synthesized by sol-gel dipcoating followed by a high-temperature post-deposition thermal annealing procedure. At high temperatures, a competitive growth process takes place that allows to obtain thin films made of atomically flat islands with an in-plane diameter typically ten times higher than the thickness or on the contrary inducing the formation of dome-shaped islands. Apart from having a different shape, these islands are also characterized by a different crystallographic orientation with respect to the substrates respectively (00 1) and (I 11). In this paper, we investigate the influence of the substrate surface roughness on this competitive grain growth process. The deposition on epi-polished substrates results in a two-dimensional (21)) island growth, whereas the deposition on rough substrates results in a three-dimensional (31)) growth of dome-shaped nanosized islands. The films have been characterized by atomic force microscopy and high-resolution X-ray diffraction using the reciprocal space mapping technique. C 2007 Elsevier B.V. All rights reserved.