화학공학소재연구정보센터
Materials Chemistry and Physics, Vol.105, No.1, 105-113, 2007
The use of water-soluble hydrazones as inhibitors for the corrosion of C-steel in acidic medium
Inhibition efficiency of some water-soluble hydrazones for C-steel corrosion in hydrochloric acid has been tested by weight loss, polarisation measurements and open circuit technique. The inhibition effect was attributed to the adsorption of the additives on the C-steel surface as supported by adsorption measurements at Pt electrode using cyclic voltarnmetry. Electrochemical measurements indicated that all the additives behave as cathodic-type inhibitors. The data obtained fit well to both the Temkin adsorption isotherm and the kinetic-thermodynamic model. The inhibition behaviour and its order were explained with the help of the proposed skeletal representation. (c) 2007 Elsevier B.V. All rights reserved.