화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.14, No.5, 535-563, September, 2008
DOI10.1016/j.jiec.2008.06.011  Export Citation
Polymer micro and nanocomposites: Structure, interactions, properties
Janos Moczo1, 2, and Bela Pukanszky1, 2, †
  • 1Laboratory of Plastics and Rubber Technology, Department of Physical Chemistry and Materials Science, Budapest University of Technology and Economics, H-1521 Budapest, P.O. Box 91, Hungary
  • 2Institute of Materials and Environmental Chemistry, Chemical Research Center, Hungarian Academy of Sciences, H-1525 Budapest, P.O. Box 17, Hungary
E-mail:
The characteristics of all heterogeneous polymer systems including composites containing either micro or nanofillers are determined by four factors: component properties, composition, structure and interfacial interactions. The most important filler characteristics are particle size, size distribution, specific surface area and particle shape, while the main matrix property is stiffness. Segregation, aggregation and the orientation of anisotropic particles determine structure. Interfacial interactions lead to the formation of a stiff interphase considerably influencing properties. Interactions are changed by surface modification, which must be always system specific and selected according to its goal. Under the effect of external load inhomogeneous stress distribution develops around heterogeneities, which initiate local micromechanical deformation processes determining the macroscopic properties of the composites. In filled polymers the dominating deformation mechanism is usually debonding. Nanocomposites represent one of the new classes of materials, but further research and development is needed before they gain significant position in the market.
Keywords:Particulate filled polymers;Layered silicate nanocomposites;Structure.property correlations;Interfacial interactions;Models
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