Radiolytic synthesis of Pd-M (M = Ag, Au, Cu, Ni and Pt) alloy nanoparticles and their use in reduction of 4-nitrophenol

Seong-Dae Oh; Mi-Ran Kim; Seong-Ho Choi; Jong-Han Chun; Kwang-Pill Lee; A. Gopalan; Chul-Gyun Hwang; Kim Sang-Ho; Oh Ji Hoon

Journal of Industrial and Engineering Chemistry, Vol.14, No.5, 687-692, September, 2008

DOI10.1016/j.jiec.2008.04.008 Export Citation

Radiolytic synthesis of Pd-M (M = Ag, Au, Cu, Ni and Pt) alloy nanoparticles and their use in reduction of 4-nitrophenol

Seong-Dae Oh, Mi-Ran Kim, Seong-Ho Choi^†, Jong-Han Chun¹, Kwang-Pill Lee², A. Gopalan², Chul-Gyun Hwang³, Kim Sang-Ho³, and Oh Ji Hoon³

Department of Chemistry, BK 21 NanoBiosensor Research Team, Hannam University, Daejeon 305-811, Republic of Korea
¹Department of Applied Chemistry, Hanbat National Univerisity, Daejeon 305-719, Republic of Korea
²Department of Chemistry Graduate School, Kyungpook National University, Daegu 702-701, Republic of Korea
³Nano Practical Application Center, Daegu New Technology Agency, Daegu 704-801, Republic of Korea

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Polyvinylpyrrolidone, PVP, stabilized Pd-M (M = Ag, Au, Cu, Ni and Pt) alloy colloids are successfully prepared by g-irradiation in aqueous solution. PVP-stabilized Pd.M colloids are characterized by field-emission transmission electron microscopy (FE-TEM) and energy dispersive Xray spectroscopy (EDXS). The catalytic efficiency of Pd and Pd-M alloy colloids is analyzed for the reduction of 4-nitrophenol in aqueous solution at room temperature. The catalytic efficiency of Pd.M alloy nanoparticles takes the following order: Pd > Pd-Cu ~ Pd-Ni > Pd-Ag ~ Pd-Au > Pd-Pt.

Keywords:γ-Irradiation;Pd-Cu alloy colloids;Pd-Ni alloy colloids;Pd-Ag alloy colloids;Pd-Au alloy colloids;Pd-Pt alloy colloids

[References]

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Henglein A, Chem. Rev., 1861, 89 (1989)
Kim JS, J. Ind. Eng. Chem., 13(5), 718 (2007)
Burda C, Chen XB, Narayanan R, El-Sayed MA, Chem. Rev., 105(4), 1025 (2005)
Sau TK, Murphy CJ, J. Am. Chem. Soc., 126, 8684 (2004)
Ahmadi TS, Wang ZL, Green TC, Henglein A, Elsayed MA, Science, 272(5270), 1924 (1996)
Henglein A, Giersig M, J. Phys. Chem. B, 103(44), 9533 (1999)
Puntes VF, Krishnan KM, Alivisatos AP, Science, 291(5511), 2115 (2001)
Choi SH, J. Ind. Eng. Chem., 10(6), 1015 (2004)
Oh SD, Yoon KR, Choi SH, Gopalan A, Lee KP, Sohn SH, Kang HD, Choi IS, J. Non-Cryst. Solids, 355, 352 (2006)
Oh SD, So BK, Choi SH, Gopalan A, Lee KP, Yoon KR, Choi IS, Mater. Lett., 59, 1121 (2005)
Ding J, Chan KY, Ren JW, Xiao FS, Electrochim. Acta, 50(15), 3131 (2005)
Rojas S, Garcia-Garcia FJ, Jaras S, Martinez-Huerta MV, Fierro JLG, Boutonnet M, Appl. Catal. A: Gen., 285(1-2), 24 (2005)
Pradhan N, Pal A, Pal T, Colloids Surf. A, 196, 247 (2002)
Neilson AH, The Handbook of Environmental Chemistry, vol. 3: Anthropogenic Compounds, Part J: PAHs and Related Compounds: Biology, Lewis Publishers, Boca Raton, FL, 1997, p. 346
Schwab CE, Huber WW, Parzefall W, Hietsch G, Kassie F, Schulte-Hermann R, Knasmuller S, Crit. Rev. Toxicol., 30, 1 (2000)
Xu SG, Xi XL, Shi J, Cao SK, J. Mol. Catal. A-Chem., 160(2), 287 (2000)
Downing RS, Kunkeler PJ, Vanbekkum H, Catal. Today, 37(2), 121 (1997)
Deshpande RM, Mahajan AN, Diwakar MM, Ozarde PS, Chaudhari RV, J. Org. Chem., 69, 4835 (2004)
Regan MR, Banerjee IA, Scripta Mater., 54, 909 (2006)

[Referenced By]

[1] Halperin WP, Rev. Mod. Phys., 533, 58 (1986)

[2] Henglein A, Chem. Rev., 1861, 89 (1989)

[3] Kim JS, J. Ind. Eng. Chem., 13(5), 718 (2007)

[4] Burda C, Chen XB, Narayanan R, El-Sayed MA, Chem. Rev., 105(4), 1025 (2005)

[5] Sau TK, Murphy CJ, J. Am. Chem. Soc., 126, 8684 (2004)

[6] Ahmadi TS, Wang ZL, Green TC, Henglein A, Elsayed MA, Science, 272(5270), 1924 (1996)

[7] Henglein A, Giersig M, J. Phys. Chem. B, 103(44), 9533 (1999)

[8] Puntes VF, Krishnan KM, Alivisatos AP, Science, 291(5511), 2115 (2001)

[9] Choi SH, J. Ind. Eng. Chem., 10(6), 1015 (2004)

[10] Oh SD, Yoon KR, Choi SH, Gopalan A, Lee KP, Sohn SH, Kang HD, Choi IS, J. Non-Cryst. Solids, 355, 352 (2006)

[11] Oh SD, So BK, Choi SH, Gopalan A, Lee KP, Yoon KR, Choi IS, Mater. Lett., 59, 1121 (2005)

[12] Ding J, Chan KY, Ren JW, Xiao FS, Electrochim. Acta, 50(15), 3131 (2005)

[13] Rojas S, Garcia-Garcia FJ, Jaras S, Martinez-Huerta MV, Fierro JLG, Boutonnet M, Appl. Catal. A: Gen., 285(1-2), 24 (2005)

[14] Pradhan N, Pal A, Pal T, Colloids Surf. A, 196, 247 (2002)

[15] Neilson AH, The Handbook of Environmental Chemistry, vol. 3: Anthropogenic Compounds, Part J: PAHs and Related Compounds: Biology, Lewis Publishers, Boca Raton, FL, 1997, p. 346

[16] Schwab CE, Huber WW, Parzefall W, Hietsch G, Kassie F, Schulte-Hermann R, Knasmuller S, Crit. Rev. Toxicol., 30, 1 (2000)

[17] Xu SG, Xi XL, Shi J, Cao SK, J. Mol. Catal. A-Chem., 160(2), 287 (2000)

[18] Downing RS, Kunkeler PJ, Vanbekkum H, Catal. Today, 37(2), 121 (1997)

[19] Deshpande RM, Mahajan AN, Diwakar MM, Ozarde PS, Chaudhari RV, J. Org. Chem., 69, 4835 (2004)

[20] Regan MR, Banerjee IA, Scripta Mater., 54, 909 (2006)