Reduction of aromatic nitro compounds on Pd colloids prepared by γ-irradiation

Chul-Gyun Hwang; Kim Sang-Ho; Oh Ji Hoon; Mi-Ran Kim; Seong-Ho Choi

Journal of Industrial and Engineering Chemistry, Vol.14, No.6, 864-868, November, 2008

DOI10.1016/j.jiec.2008.05.010 Export Citation

Reduction of aromatic nitro compounds on Pd colloids prepared by γ-irradiation

Chul-Gyun Hwang, Kim Sang-Ho, Oh Ji Hoon, Mi-Ran Kim¹, and Seong-Ho Choi^{1, †}

Nano Practical Application Center, Daegu New Technology Agency, Daegu 704-801, Republic of Korea
¹Department of Chemistry, BK 21 NanoBiosensor Research Team, Hannam University, Daejeon 305-811, Republic of Korea

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Poly(vinylpyrrolidone) (PVP), stabilized Pd colloids were successfully prepared by γ-irradiation in aqueous solution without additional reducing agent. The ‘clean’ Pd colloid was used as catalysts for the reduction of 2-, 3-, 4-nitrophenol, 2,4,6-trinitrotoluene, and 4-nitrobenzo-15- crown in aqueous solution at room temperature. The reduction process was monitored by UV-Visible spectroscopy.

Keywords:γ-Irradiation;Pd colloids;2-. 3-. 4-Nitrophenol;2. 4. 6-Trinitrotoluene;4-Nitrobeno-15-crown

[References]

Halperin WP, Rev. Mod. Phys., 533, 58 (1986)
Henglein A, Chem. Rev., 1861, 89 (1989)
Choi SH, J. Ind. Eng. Chem., 10(6), 1015 (2004)
Lee D, Cho SI, Kim GJ, Kim H, Lee IM, J. Ind. Eng. Chem., 1067, 13 (2007)
Oh SD, Yoon KR, Choi SH, Gopalan A, Lee KP, Sohn SH, Kang HD, Choi IS, J. Non-Cryst. Solids, 355, 352 (2006)
Oh SD, So BK, Choi SH, Gopalan A, Lee KP, Yoon KR, Choi IS, Mater. Lett., 59, 1121 (2005)
Yu KMK, Meric P, Tsang SC, Catal. Today, 114(4), 428 (2006)
Silvestre-Albero J, Rupprechter G, Freund HJ, J. Catal., 240(1), 58 (2006)
Barbaro P, Bianchini C, Dal Santo V, Meli A, Moneti S, Psaro R, Scaffidi A, Sordelli L, Vizza F, J. Am. Chem. Soc., 128(21), 7065 (2006)
Ding J, Chan KY, Ren JW, Xiao FS, Electrochim. Acta, 50(15), 3131 (2005)
Rojas S, Garcia-Garcia FJ, Jaras S, Martinez-Huerta MV, Fierro JLG, Boutonnet M, Appl. Catal. A: Gen., 285(1-2), 24 (2005)
Remita S, Mostafavi M, Delcourt MO, Rad. Phys. Chem., 47, 275 (1996)
Brust M, Walker M, Bethell D, Schiffrin DJ, Whyman R, J. Chem. Soc., Chem. Commun. (1994) 801
Huang HH, Ni XP, Loy GL, Chew CH, Tan KL, Loh FC, Deng JF, Xu GQ, Langmuir, 12(4), 909 (1996)
Boudjahem AG, Monteverdi S, Mercy M, Bettahar MM, J. Catal., 221(2), 325 (2004)
Kim SJ, Oh SD, Choi SH, Gopalan AL, Lee KP, Kang HD, Shin CH, Korean J. Chem. Eng., 23(3), 488 (2006)
Neilson AH, The Handbook of Environmental Chemistry, Volume 3: Anthropogenic Compounds Part J: PAHs and Related Compounds: Biology, Lewis Publishers, Boca Raton, FL, 1997, p. 346
Schwab CE, Huber WW, Parzefall W, Hietsch G, Kassie F, Schulte-Hermann R, Knasmuller S, Critic. Rev. Toxicol., 30, 1 (2000)
Xu SG, Xi XL, Shi J, Cao SK, J. Mol. Catal. A-Chem., 160(2), 287 (2000)
Downing RS, Kunkeler PJ, Vanbekkum H, Catal. Today, 37(2), 121 (1997)
Deshpande RM, Mahajan AN, Diwakar MM, Ozarde PS, Chaudhari RV, J. Org. Chem., 69, 4835 (2004)
Pradhan N, Pal A, Pal T, Colloids Surf. A, 196, 247 (2002)
Pradhan N, Pal A, Pal T, Langmuir, 17(5), 1800 (2001)
Hamidinia SA, Steinbaugh GE, Erdahl WL, Taylor RW, Pfeiffer DR, J. Inorg. Biochem., 100, 403 (2006)

[Referenced By]

[1] Halperin WP, Rev. Mod. Phys., 533, 58 (1986)

[2] Henglein A, Chem. Rev., 1861, 89 (1989)

[3] Choi SH, J. Ind. Eng. Chem., 10(6), 1015 (2004)

[4] Lee D, Cho SI, Kim GJ, Kim H, Lee IM, J. Ind. Eng. Chem., 1067, 13 (2007)

[5] Oh SD, Yoon KR, Choi SH, Gopalan A, Lee KP, Sohn SH, Kang HD, Choi IS, J. Non-Cryst. Solids, 355, 352 (2006)

[6] Oh SD, So BK, Choi SH, Gopalan A, Lee KP, Yoon KR, Choi IS, Mater. Lett., 59, 1121 (2005)

[7] Yu KMK, Meric P, Tsang SC, Catal. Today, 114(4), 428 (2006)

[8] Silvestre-Albero J, Rupprechter G, Freund HJ, J. Catal., 240(1), 58 (2006)

[9] Barbaro P, Bianchini C, Dal Santo V, Meli A, Moneti S, Psaro R, Scaffidi A, Sordelli L, Vizza F, J. Am. Chem. Soc., 128(21), 7065 (2006)

[10] Ding J, Chan KY, Ren JW, Xiao FS, Electrochim. Acta, 50(15), 3131 (2005)

[11] Rojas S, Garcia-Garcia FJ, Jaras S, Martinez-Huerta MV, Fierro JLG, Boutonnet M, Appl. Catal. A: Gen., 285(1-2), 24 (2005)

[12] Remita S, Mostafavi M, Delcourt MO, Rad. Phys. Chem., 47, 275 (1996)

[13] Brust M, Walker M, Bethell D, Schiffrin DJ, Whyman R, J. Chem. Soc., Chem. Commun. (1994) 801

[14] Huang HH, Ni XP, Loy GL, Chew CH, Tan KL, Loh FC, Deng JF, Xu GQ, Langmuir, 12(4), 909 (1996)

[15] Boudjahem AG, Monteverdi S, Mercy M, Bettahar MM, J. Catal., 221(2), 325 (2004)

[16] Kim SJ, Oh SD, Choi SH, Gopalan AL, Lee KP, Kang HD, Shin CH, Korean J. Chem. Eng., 23(3), 488 (2006)

[17] Neilson AH, The Handbook of Environmental Chemistry, Volume 3: Anthropogenic Compounds Part J: PAHs and Related Compounds: Biology, Lewis Publishers, Boca Raton, FL, 1997, p. 346

[18] Schwab CE, Huber WW, Parzefall W, Hietsch G, Kassie F, Schulte-Hermann R, Knasmuller S, Critic. Rev. Toxicol., 30, 1 (2000)

[19] Xu SG, Xi XL, Shi J, Cao SK, J. Mol. Catal. A-Chem., 160(2), 287 (2000)

[20] Downing RS, Kunkeler PJ, Vanbekkum H, Catal. Today, 37(2), 121 (1997)

[21] Deshpande RM, Mahajan AN, Diwakar MM, Ozarde PS, Chaudhari RV, J. Org. Chem., 69, 4835 (2004)

[22] Pradhan N, Pal A, Pal T, Colloids Surf. A, 196, 247 (2002)

[23] Pradhan N, Pal A, Pal T, Langmuir, 17(5), 1800 (2001)

[24] Hamidinia SA, Steinbaugh GE, Erdahl WL, Taylor RW, Pfeiffer DR, J. Inorg. Biochem., 100, 403 (2006)