화학공학소재연구정보센터
Journal of the Korean Industrial and Engineering Chemistry, Vol.20, No.1, 1-8, February, 2009
촉매 접촉 분해법을 활용한 바이오오일 개질 연구 동향
Research and Development Trends on Bio-oil Upgrading via Catalytic Vapor Cracking
E-mail:
초록
바이오오일은 고부가가치 화학물질이나 차세대 탄화수소 연료 생산을 위한 석유정제시설의 연료로서 사용이 가능하기 때문에 전도유망한 신재생 에너지원 가운데 하나로 상당한 관심을 불러일으키고 있다. 바이오오일을 석유정제시설에 공급하기 위해서는 전처리 과정으로 안정화 공정이 필요하며, 이를 위한 방법 가운데 현재로서는 촉매 접촉 분해법이 잠재성이 가장 높은 것으로 인식되고 있다. 본 총설에서는 촉매 접촉 분해법을 활용한 바이오오일 개질에 관한 최근 연구 동향을 적용된 촉매의 성능과 개질 방법을 중심으로 소개하고자 한다.
Bio-oil has attracted considerable interest as one of the promising renewable energy resources because it can be used as a feedstock in conventional petroleum refineries for the production of high value chemicals or next-generation hydrocarbon fuels. Currently, catalytic vapor cracking is considered the most potential upgrading method for stabilization of bio-oil, which is a pre-process required prior to feeding bio-oil into refineries. This review introduces the recent research and development trends on bio-oil upgrading via catalytic vapor cracking, focusing on catalysts and upgrading methods used.
  1. IEA, Renewable energy: RD&D priorities (insights from IEA technology programmes) (2006)
  2. Park HJ, Dong JI, Jeon JK, Park YK, Yoo KS, Kim SS, Kim J, Kim S, Chem. Eng. J., 143, 124 (2008)
  3. Park HJ, Park YK, Dong JI, Kim JS, Jeon JK, Kim SS, Kim J, Song B, Park J, Lee KJ, Fuel. Proces. Technol., 90, 186 (2009)
  4. Perez MG, Chaala A, Roy C, J. Anal. Appl. Pyrolysis, 65, 111 (2002)
  5. Demirbas A, Energy Conv. Manag., 42(11), 1357 (2001)
  6. McKendry P, Bioresour. Technol., 83(1), 37 (2002)
  7. Czernik S, Bridgwater AV, Energy Fuels, 18(2), 590 (2004)
  8. Mohan D, Pittman CU, Steele PH, Energy Fuels, 20(3), 848 (2006)
  9. Czernik S, Maggi R, Peacocke GVC, Fast Pyrolysis of Biomass: A Handbook, ed. Bridgewater AV, 2, 141, CPL Press, Newbury (2002)
  10. Bridgwater AV, Catal. Today, 29(1-4), 285 (1996)
  11. ADJAYE JD, BAKHSHI NN, Biomass Bioenerg., 8(3), 131 (1995)
  12. ADJAYE JD, BAKHSHI NN, Biomass Bioenerg., 8(4), 265 (1995)
  13. ADJAYE JD, BAKHSHI NN, Fuel Process. Technol., 45(3), 161 (1995)
  14. ADJAYE JD, BAKHSHI NN, Fuel Process. Technol., 45(3), 185 (1995)
  15. Vitolo S, Seggiani M, Frediani P, Ambrosini G, Politi L, Fuel, 78(10), 1147 (1999)
  16. Vitolo S, Bresci B, Seggiani M, Gallo MG, Fuel, 80, 17 (2001)
  17. Gayubo AG, Aguayo AT, Atutxa A, Aguado R, Bilbao J, Ind. Eng. Chem. Res., 43(11), 2610 (2004)
  18. Gayubo AG, Aguayo AT, Atutxa A, Aguado R, Olazar M, Bilbao J, Ind. Eng. Chem. Res., 43(11), 2619 (2004)
  19. Gayubo AG, Aguayo AT, Atutxa A, Prieto R, Bilbao J, Energy Fuels, 18(6), 1640 (2004)
  20. Samolada MC, Baldauf W, Vasalos IA, Fuel, 77(14), 1667 (1998)
  21. Samolada MC, Papafotica A, Vasalos IA, Energy Fuels, 14(6), 1161 (2000)
  22. Twaiq FA, Zabidi NAM, Bhatia S, Ind. Eng. Chem. Res., 38(9), 3230 (1999)
  23. Park HJ, Dong JI, Jeon JK, Yoo KS, Yim JS, Sohn JM, Park YK, J. Ind. Eng. Chem., 13(2), 182 (2007)
  24. Williams PT, Horne PA, Fuel, 74, 1839 (1995)
  25. Horne PA, Williams PT, Fuel, 75, 1043 (1996)
  26. Horne PA, Nugranad N, Williams PT, J. Anal. Appl. Pyrolysis, 34, 87 (1995)
  27. Williams PT, Nugranad N, Energy, 25(6), 493 (2000)
  28. Aho A, Kumar N, Eranen K, Salmi T, Hupa M, Murzin DY, Process Saf. Environ. Protect., 85, 473 (2007)
  29. Aho A, Kumar N, Eranen K, Salmi T, Hupa M, Murzin DY, Fuel, 87, 2493 (2008)
  30. Fabbri D, Torri C, Baravelli V, J. Anal. Appl. Pyrolysis, 80, 24 (2007)
  31. Lappas AA, Samolada MC, Iatridis DK, Voutetakis SS, Vasalos IA, Fuel, 81, 2087 (2002)
  32. Zhang H, Xiao R, Huang H, Xiao G, Bioresour. Technol., 100, 1428 (2009)
  33. Demiral I, Sensoz S, Bioresour. Technol., 99, 8002 (2008)
  34. Ariga K, Hill JP, Lee MV, Viny A, Charvet R, Aharya S, Sci. Technol. Adv. Mater., 9, 014109 (2008)
  35. Twaiq FA, Zabidi NAM, Mohamed AR, Bhatia S, Fuel Process. Technol., 84(1-3), 105 (2003)
  36. Twaiq FA, Mohamed AR, Bhatia S, Micropor. Mesopor. Mater., 64, 95 (2003)
  37. Adam J, Blazso M, Meszaros E, Stocker M, Nilsen MH, Bouzga A, Hustad JE, Grønli M, Øye G, Fuel, 84, 1494 (2005)
  38. Adam J, Antonakou E, Lappas A, Stocker M, Nilsen MH, Bouzga A, Hustad JE, Øye G, Micropor. Mesopor. Mater., 96, 93 (2006)
  39. Antonakou E, Lappas A, Nilsen MH, Bouzga A, Stocker M, Fuel, 85, 2202 (2006)
  40. Nilsen MH, Antonakou E, Bouzga A, Lappas A, Mathisen K, Stocker M, Micropor. Mesopor. Mater., 105, 189 (2007)
  41. Iliopoulou EF, Antonakou EV, Karakoulia SA, Vasalos IA, Lappas AA, Triantafyllidis KS, Chem. Eng. J., 134(1-3), 51 (2007)
  42. Zhang Z, Han Y, Zhu L, Wang R, Yu Y, Qiu S, Zhao D, Xiao FS, Angew. Chem. Int. Ed., 40, 1258 (2001)
  43. Triantafyllidis KS, Iliopoulou EF, Antonakou EV, Lappas AA, Wang H, Pinnavaia TJ, Micropor. Mesopor. Mater., 99, 132 (2007)
  44. Lee HI, Park HJ, Park YK, Hur JY, Jeon JK, Kim JM, Catal. Today, 132, 68 (2008)
  45. Park HJ, Jeon JK, Kim JM, Lee HI, Yim JH, Park J, Park YK, J. Nanosci. Nanotech, 8, 5439 (2008)