Synthesis of CdS nanoparticles dispersed within solutions and polymer films using amphiphilic urethane acrylate chains

Ju-Young Kim; Hong-Mo Koo; Kyo-Jin Ihn; Kyung-Do Suh

Journal of Industrial and Engineering Chemistry, Vol.15, No.1, 103-109, January, 2009

DOI10.1016/j.jiec.2008.08.005 Export Citation

Synthesis of CdS nanoparticles dispersed within solutions and polymer films using amphiphilic urethane acrylate chains

Ju-Young Kim , Hong-Mo Koo¹, Kyo-Jin Ihn², and Kyung-Do Suh^{1, †}

Department of Advanced Materials Engineering, Kangwon National University, Samcheok, Kangwon 245-711, Republic of Korea
¹Department of Chemical Engineering, College of Engineering Hanyang University, Seoul 133-791, Republic of Korea
²Department of Chemical Engineering, Kangwon National University, Chunchon, Kangwon 200-701, Republic of Korea

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In this study, a newprocess for preparation of CdS/polymer nanocomposite films using a newamphiphilic oligomer chain (Urethane Acrylate Nonionomer: UAN) is presented. UAN chains have hydrophilic polyethylene oxide segments and polypropylene oxide-based hydrophobic segments as part of the same backbone. In addition, these chains also have reactive vinyl groups at their hydrophobic segments. For the preparation of CdS nano-colloid solutions, UAN chains acted as a stabilizer for CdS nanoparticles dispersed in a solvent. For the fabrication of CdS/polymer nanocomposite films, UAN chains in CdS nano-colloid solutions were polymerized through reactions between their vinyl groups, resulting inthe formation of CdS nanoparticle dispersed films swollen by the solvent. The nature of the solvent used strongly influenced the size of the CdS nanoparticles, which was confirmedbyUVabsorption spectra, PL emission spectra and TEM images.Smaller sized CdS nanoparticles were formedin higher polar solvents such asDMAc and methanol, which can be explained by the higher solubility of UAN chains and the more effective dissociation and stabilization of cadmium salts and CdS nanoparticles by UAN chains in the polar solvent.

Keywords:CdS nanoparticles;Urethane acrylate nonionomer;Amphiphilic molecules

[References]

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Park M, Chin BD, Yu JW, Chun MS, Han SH, J. Ind. Eng. Chem., 14(3), 382 (2008)
Shim JK, Park IS, Kim JY, J. Ind. Eng. Chem., 13(6), 917 (2007)
Fasol G, Science, 280(5363), 545 (1998)
Pattabi M, Uchil J, Sol. Energy Mater. Sol. Cells, 63, 309 (2000)
Zhao H, Douglas EP, Chem. Mater., 14, 1418 (2003)
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Resch U, Eychmuller A, Haase M, Wller H, Langmuir, 8, 2215 (1992)
Liu B, Li H, Chew CH, Que W, Lam YL, Kam CH, Gan LM, Xu GQ, Mater. Lett., 51, 461 (2001)
Holmberg K, J. Colloid Interface Sci., 274(2), 355 (2004)
Esumi K, Hosoya T, Suzuki A, Torigoe K, J. Colloid Interface Sci., 226(2), 346 (2000)
Faul CFJ, Anotonietti M, Hentze HP, Smarsly B, Colloids Surf. A, 212, 115 (2003)
Huang JM, Yang Y, Yang B, Liu SY, Shen JC, Thin Solid Films 327-329 (1998) 536
Moffitt M, Vali H, Eisenberg A, Chem. Mater., 10, 1021 (1998)
Kane RS, Cohen RE, Silbey R, Langmuir, 15(1), 39 (1999)
Kane RS, Cohen RE, Silbey R, Chem. Mater., 8, 1919 (1996)
Qi L, Colfen H, Antonietti M, Nano Lett., 1, 65 (2001)
Zhao H, Douglas EP, Harrison BS, Schanze KS, Langmuir, 17, 8426 (2001)
Forster S, Antonietti M, Adv. Mater., 10(3), 195 (1998)
Mayer ABR, Polym. Adv. Technol., 12, 96 (2001)
Beecroft LL, Ober CK, Chem. Mater., 9, 1302 (1997)
Caseri W, Macromol. Rapid Commun., 21(11), 705 (2000)
Gangopadhyay R, De A, Chem. Mater., 12, 608 (2000)
Spatz JP, Roescher A, Moller M, Adv. Mater., 8(4), 337 (1996)
Sooklal K, Hanus LH, Ploehn HJ, Murphy CJ, Adv. Mater., 10(14), 1083 (1998)
Hedden RC, Bauer BJ, Smith AP, Grohn F, Amis E, Polymer, 43(20), 5473 (2002)
Kim JY, Shin DH, Ihn KJ, Nam CW, Macromol. Chem. Phys., 203, 2454 (2002)
Kim JY, Shin DH, Ihn KJ, Macromol. Chem. Phys., 206, 794 (2005)
Kim JY, Kim HM, Shin DH, Ihn KJ, Macromol. Chem. Phys., 207, 925 (2006)
Yang Y, Chen HL, Bao XM, J. Cryst. Growth, 252(1-3), 251 (2003)
Carrot G, Scholz SM, Plummer CJG, Hilborn JG, Hedrick JL, Chem. Mater., 11, 3571 (1999)
Kuczynski J, Thomas JK, J. Phys. Chem., 89, 2720 (1985)
Solomons TWG, Fundamentals of Organic Chemistry, 2nd ed., John Wiley & Sons, New York (1986)
Hara M, in: Hara M (Ed.), Polyelectrolytes Science and Technology, Marcel Dekker, New York (1993)
Nomula S, Cooper SL, J. Colloid Interface Sci., 205(2), 331 (1998)
Hara M, Wu JL, in: Utracki LA, Weiss A (Eds.), Proc. ACS Symposium Series 395. Multiphase Polymers, Blends and Ionomers, American Chemical Society, Washington, DC (1989)
Kim JY, Kim CH, Yoo DJ, Suh KD, J. Polym. Sci. B: Polym. Phys., 38(14), 1903 (2000)
Kim JY, Chon YS, Yoo DJ, Suh KD, J. Polym. Sci. B: Polym. Phys., 38(16), 2081 (2000)

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[2] Park M, Chin BD, Yu JW, Chun MS, Han SH, J. Ind. Eng. Chem., 14(3), 382 (2008)

[3] Shim JK, Park IS, Kim JY, J. Ind. Eng. Chem., 13(6), 917 (2007)

[4] Fasol G, Science, 280(5363), 545 (1998)

[5] Pattabi M, Uchil J, Sol. Energy Mater. Sol. Cells, 63, 309 (2000)

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[7] Lee G, Curri ML, Cola A, Catalano M, Lomascolo M, Manna L, Quaranta F, Agostiano A, Farinola GM, Babudri F, Naso F, Monica MD, Vasanelli L, Mater. Sci. Eng., B, 74, 175 (2000)

[8] Murakoshi K, Hosokawa H, Saitoh M, Wada Y, Sakata T, Mori H, Satoh M, Yanagida SJ, Chem. Soc. Faraday Trans., 94, 579 (1998)

[9] Resch U, Eychmuller A, Haase M, Wller H, Langmuir, 8, 2215 (1992)

[10] Liu B, Li H, Chew CH, Que W, Lam YL, Kam CH, Gan LM, Xu GQ, Mater. Lett., 51, 461 (2001)

[11] Holmberg K, J. Colloid Interface Sci., 274(2), 355 (2004)

[12] Esumi K, Hosoya T, Suzuki A, Torigoe K, J. Colloid Interface Sci., 226(2), 346 (2000)

[13] Faul CFJ, Anotonietti M, Hentze HP, Smarsly B, Colloids Surf. A, 212, 115 (2003)

[14] Huang JM, Yang Y, Yang B, Liu SY, Shen JC, Thin Solid Films 327-329 (1998) 536

[15] Moffitt M, Vali H, Eisenberg A, Chem. Mater., 10, 1021 (1998)

[16] Kane RS, Cohen RE, Silbey R, Langmuir, 15(1), 39 (1999)

[17] Kane RS, Cohen RE, Silbey R, Chem. Mater., 8, 1919 (1996)

[18] Qi L, Colfen H, Antonietti M, Nano Lett., 1, 65 (2001)

[19] Zhao H, Douglas EP, Harrison BS, Schanze KS, Langmuir, 17, 8426 (2001)

[20] Forster S, Antonietti M, Adv. Mater., 10(3), 195 (1998)

[21] Mayer ABR, Polym. Adv. Technol., 12, 96 (2001)

[22] Beecroft LL, Ober CK, Chem. Mater., 9, 1302 (1997)

[23] Caseri W, Macromol. Rapid Commun., 21(11), 705 (2000)

[24] Gangopadhyay R, De A, Chem. Mater., 12, 608 (2000)

[25] Spatz JP, Roescher A, Moller M, Adv. Mater., 8(4), 337 (1996)

[26] Sooklal K, Hanus LH, Ploehn HJ, Murphy CJ, Adv. Mater., 10(14), 1083 (1998)

[27] Hedden RC, Bauer BJ, Smith AP, Grohn F, Amis E, Polymer, 43(20), 5473 (2002)

[28] Kim JY, Shin DH, Ihn KJ, Nam CW, Macromol. Chem. Phys., 203, 2454 (2002)

[29] Kim JY, Shin DH, Ihn KJ, Macromol. Chem. Phys., 206, 794 (2005)

[30] Kim JY, Kim HM, Shin DH, Ihn KJ, Macromol. Chem. Phys., 207, 925 (2006)

[31] Yang Y, Chen HL, Bao XM, J. Cryst. Growth, 252(1-3), 251 (2003)

[32] Carrot G, Scholz SM, Plummer CJG, Hilborn JG, Hedrick JL, Chem. Mater., 11, 3571 (1999)

[33] Kuczynski J, Thomas JK, J. Phys. Chem., 89, 2720 (1985)

[34] Solomons TWG, Fundamentals of Organic Chemistry, 2nd ed., John Wiley & Sons, New York (1986)

[35] Hara M, in: Hara M (Ed.), Polyelectrolytes Science and Technology, Marcel Dekker, New York (1993)

[36] Nomula S, Cooper SL, J. Colloid Interface Sci., 205(2), 331 (1998)

[37] Hara M, Wu JL, in: Utracki LA, Weiss A (Eds.), Proc. ACS Symposium Series 395. Multiphase Polymers, Blends and Ionomers, American Chemical Society, Washington, DC (1989)

[38] Kim JY, Kim CH, Yoo DJ, Suh KD, J. Polym. Sci. B: Polym. Phys., 38(14), 1903 (2000)

[39] Kim JY, Chon YS, Yoo DJ, Suh KD, J. Polym. Sci. B: Polym. Phys., 38(16), 2081 (2000)