세제용 고기능성 계면활성제의 개발 및 응용 동향

랑문정; Moon-Jeong Rang

Journal of the Korean Industrial and Engineering Chemistry, Vol.20, No.2, 126-133, April, 2009

Export Citation

세제용 고기능성 계면활성제의 개발 및 응용 동향

Trend on Development and Application of High Performance Surfactants for Detergents

랑문정^†

배재대학교 분자과학부

Moon-Jeong Rang^†

Division of Molecular Science, Pai Chai University, Daejeon 302-735, Korea

E-mail:

초록

가정용 및 산업용 세정제품에 주성분으로 사용되고 있는 계면활성제는 유화, 가용화, 분산, 세정, 습윤, 기포 등의 기본 기능뿐만 아니라 경제성, 인체 및 환경 안전성의 요건을 충족해야 하며, 최근에는 지속가능발전이라는 관점에서 계면활성제의 제조 및 사용환경조건에서 원료자원, 에너지, 폐기물을 가능한 절약하여야 한다. 이러한 사회적 경제적 환경변화에 부응하기 위하여 새로운 고기능 계면활성제 개발이 활발하게 이루어지고 있으며, 현재까지 기존 계면활성제의 분자 구조 조정에 의한 용해성 및 계면활성 증가 그리고 혼합 계면활성제 시스템에 의한 계면활성 상승작용에서 괄목할 만한 성과가 이루어 졌다. 본 총설에서는 최근에 도출된 다양한 연구개발 결과 중 기술적 발전 및 산업화 응용측면에서 의미가 있는 고기능 계면활성제들의 개발 및 응용현황에 대하여 논의한다.

The surfactants applied in household detergents and industrial cleansers should satisfy the requirement of not just the basic function such as emulsification, solubilisation, dispersion, detergency, wetting and foaming, but also the economical efficiency and the safety to human and environment. In the viewpoint of the sustainable development, the surfactants, moreover, have to reduce raw materials and energy consumption and waste disposal when they are being manufactured and also consumed for their purposes. New high-performance surfactants have been extensively studied and developed in order to respond the change in social and economical environment. Noticeable progresses have been achieved so far, which are the significant increase in solubility and surface activity through the minor modification of existing surfactant molecular structure and the synergistic increase in a surface activity shown in the mixed surfactant system of anionic and cationic surfactants. In this review, the important and meaningful progresses achieved recently in technological advance and practical application will be summarized and discussed.

Keywords:high-performance surfactant;branched alkyl sulfate;2-phenyl LAS;mixed micelle;catanionic surfactant

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[1] Smulders E, Laundry Detergents, 4, Wiley-VCH, Weinheim, Germany (2002)

[2] Rang MJ, Proc. 14th Symp. Colloid and Interface Chemistry, 195, Korean Society of Industrial and Engineering Chemistry (2008)

[3] Showell MS, Handbook of Detergents Part D: Formulation, 51, Taylor & Francis, Boca Raton, Florida (2006)

[4] Watkins C, Inform, 18,780, AOCS Press, Champaign, Illinois (2007)

[5] Rosen M, Surfactants and Interfacial Phenomena, 3rd ed, 216, John Wiley & Sons, New Jersey (2004)

[6] Dolkemeyer W, Proc. 4th World Conf. Detergents, ed. Cahn A, 149, AOCS Press, Champaign, Illinois (1999)

[7] Clint JH, Surfactant Aggregation, 153, Blackie & Sons, London (1992)

[8] U. S. Patent 6,020,303 (2000)

[9] U. S. Patent 6,060,443 (2000)

[10] U. S. Patent 6,008,181 (2000)

[11] Cripe TA, Future Surfactants for Laundry Products, presented at the New Horizons for the 21st Century Conference, Williamsburg, Virginia (1998)

[12] Scheibel J, J. Surfact. Deterg., 7, 319 (2004)

[13] U. S. Patent 5,849,960 (1998)

[14] U. S. Patent 6,150,322 (2000)

[15] Schmidt WW, Surfactant Performance as a Function of Hydrophobe Branching, presented at 6th World Surfactants Congress, CESIO, Berlin, Germany (2004)

[16] Smith GA, Anantaneni P, New Water Soluble Isethionates for Personal Care, presented at SODEPEC2008, Lake Buena Vista, Florida (2008)

[17] Scott MJ, Jones MN, Biochimica et Biophysica Acta, 1508, 253 (2000)

[18] Myers D, Surfactant Science and Technology, 3rd ed., 29, John Wiley & Sons, New Jersey (2006)

[19] Bailley G, Scheibel JJ, Kott KL, Hartshorn RT, Connor DS, Stamans M, Proc. 5th World Conf. Detergents, ed. Cahn A, 115, AOCS Press, Champaign, Illinois (2003)

[20] Brent J, Standing out from the Crowd New Surfactant Molecules Create Competitive Opportunities, presented at 6th World Surfactants Congress, CESIO, Berlin, Germany (2004)

[21] Van Os NM, Kok R, Bolsman TABM, Tenside Surf. Deterg., 29, 175 (1992)

[22] Burckett J, Laurnat S, Connor D, Cripe T, Kott K, Scheibel J, Stidham R, Reilman R, Proc. 5th World Surfactants Congress, 716, CESIO, Firenze, Italy (2000)

[23] Perales JA, Manzano MA, Garrido MC, Sales D, Quiroga JM, Biodegradation, 18, 567 (2007)

[24] Cohen L, Vergara R, Moreno A, Berna JL, J. Am. Oil Chem. Soc., 72, 115 (1995)

[25] Smith DL, J. Am. Oil Chem. Soc., 74, 837 (1997)

[26] WIPO Patent WO 99,005,242 (1999)

[27] WIPO Patent WO 99,005,243 (1999)

[28] WIPO Patent WO 99,005,244 (1999)

[29] WIPO Patent WO 02,092,737 (2002)

[30] WIPO Patent WO 99,007,656 (1999)

[31] U. S. Patent 6,187,981 (2001)

[32] U. S. Patent 6,448,458 (2002)

[33] Scamehorn JF, Phenomena in Mixed Surfactant Systems, ACS Symposium Series 311, American Chemical Society, Washington, DC (1986)

[34] Holland PM, Rubingh DM, Mixed Surfactant Systems, ACS Symposium Series 501, American Chemical Society, Washington, DC (1992)

[35] Ogino K, Abe M, Mixed Surfactant Systems, Surfactant Science Series 46, Marcel Dekker, New York, NY (1993)

[36] Khan A, Marques E, Catanionic Surfactants, In Specialist Surfactants, ed. Robb ID, 37, Blackies Academic and Professional, London (1997)

[37] Abe M, Scamehorn JF, Mixed Surfactant Systems, 2nd ed., Surfactant Science Series 124, Marcel Dekker, New York, NY (2005)

[38] Dixit SG, Naik P, Encyclopedia of Surface and Colloid Science, 2nd ed., ed. Somasundaran P, 1190, Taylor & Francis, Boca Raton, Florida (2006)

[39] Rosen MJ, Surfactants and Interfacial Phenomena, 3rd ed., 379, John Wiley & Sons, Hoboken, New Jersey (2004)

[40] Choi JJ, Cho WG, Rang MJ, Korean Chem. Eng. Res., 46(4), 799 (2008)

[41] Rubingh DN, Solution Chemistry of Surfactants, ed. Mittal KL, 1, 337, Plenum, New York, New York (1979)

[42] Frese C, Ruppert S, Sugar M, Schmidt-Lewerkuhne H, Wittern KP, Fainerman VB, Eggers R, Miller R, J. Colloid Interface Sci., 267(2), 475 (2003)

[43] Fainerman VB, Lucassen-Reynols EH, Adv. Colloid Interface Sci., 96, 295 (2002)

[44] Stellner KL, Amante JC, Harwell JH, J. Colloid Interface Sci., 123, 186 (1988)

[45] Amante JC, Scamehorn JF, Harwell JH, J. Colloid Interface Sci., 144, 243 (1991)

[46] U. S. Patent 6,864,220 (2005)

[47] U. S. Patent 6,004,922 (1999)

[48] Choi JJ, Cho WG, J. Korean Oil Chemists’ Soc., 25, 23 (2008)

[49] Tsuchiya K, Ishikake J, Kim TS, Ohkubo T, Sakai H, Abe M, J. Colloid Interface Sci., 312(1), 139 (2007)