화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.26, No.3, 654-659, May, 2009
DOI10.1007/s11814-009-0109-7  Export Citation
Oxidation of cyclopentene catalyzed by tungsten-substituted molybdophosphoric acids
Jinjuan Xue, Hengbo Yin†, Haixia Li, Dongzhi Zhang, Tingshun Jiang, Longbao Yu, and Yutang Shen
  • Faculty of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, 212013, P. R. China
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A series of Keggin type tungsten-substituted molybdophosphoric acids (H3PMo12-nWnO40·XH2O) were synthesized and characterized by ICP-AES, FT-IR, TG-DSC, and XRD. The tungsten substitution extent significantly affected their catalytic activity in the oxidation of cyclopentene and the selectivity of the resultant products. The tungsten-substituted molybdophosphoric acids with tungsten substitution numbers in a range of 3-6.8 exhibited high catalytic activity in the oxidation of cyclopentene. After reaction for 8 h, the conversion of cyclopentene was up to 97%; the oxidation products mainly consisted of glutaraldehyde, cis-1,2-cyclopentanediol and trans-1,2-cyclopentanediol with the yields of ca. 23%, 27%, and 45%, respectively.
Keywords:Tungsten-substituted Molybdophosphoric Acid;Cyclopentene;Glutaraldehyde;cis-1,2-Cyclopentanediol;trans-1,2-Cyclopentanediol
  1. Yang XL, Dai WL, Chen H, Cao Y, Li HX, He HY, Fan KN, J. Catal., 229(1), 259 (2005)
  2. Chen H, Dai WL, Yang XL, Gao RH, Cao Y, Li HX, Fan KN, Appl. Catal. A: Gen., 309(1), 62 (2006)
  3. Deng J, Xu X, Chen H, Jiang A, Tetrahedron, 48, 3503 (1992)
  4. Lu Y, Yin H, Wu H, Wu H, Jiang T, Wada Y, Catal. Commun., 7, 832 (2006)
  5. Chen H, Dai WL, Deng JF, Fan KN, Catal. Lett., 81(1-2), 131 (2002)
  6. Xia X, Jin RH, He YG, Deng JF, Li HX, Appl. Surf. Sci., 165(4), 255 (2000)
  7. Jin RH, Li HX, Deng JF, J. Catal., 203(1), 75 (2001)
  8. Jin RH, Xia X, Dai WL, Deng JF, Li HX, Catal. Lett., 62(2-4), 201 (1999)
  9. Timofeeva MN, Appl. Catal. A: Gen., 256(1-2), 19 (2003)
  10. Kozhevnikov IV, Chem. Rev., 98(1), 171 (1998)
  11. Deusser LM, Petzoldt JC, Gaube JW, Hibst H, Ind. Eng. Chem. Res., 37(8), 3230 (1998)
  12. La KW, Kim H, Jung JC, Lee J, Park DR, Lee SH, Song IK, Korean J. Chem. Eng., 25(4), 710 (2008)
  13. Guo X, Huang C, Chen B, Korean J. Chem. Eng., 25(4), 675 (2008)
  14. Lim SS, Park GI, Choi JS, Song IK, Lee WY, Catal. Today, 74(3-4), 299 (2002)
  15. Inumaru K, Ono A, Kubo H, Misono M, J. Chem. Soc., Faraday Trans., 94, 1765 (1998)
  16. Khenkin AM, Weiner L, Neumann R, J. Am. Chem. Soc., 127(28), 9988 (2005)
  17. Zhang J, Tang Y, Li GY, Hu C, Appl. Catal. A: Gen., 278(2), 251 (2005)
  18. Cai XE, Du DC, Ni JP, Jin YM, Zhu J, Qian YX, Thermochim. Acta, 292(1-2), 45 (1997)
  19. Yu Z, Li S, Han F, Wang S, Zhou G, Zhang S, Kexue Tongbao (Chinese), 31, 1478 (1986)
  20. Misono M, Mizuno N, Katamura K, Kasai A, Konishi Y, Sakata K, Okuhara T, Yoneda Y, Bull. Chem. Soc. Jpn., 55, 400 (1982)
  21. Rao PM, Wolfson A, Kababya S, Vega S, Landau MV, J. Catal., 232(1), 210 (2005)
  22. Yang L, Qi YT, Yuan XD, Shen H, Kim J, J. Mol. Catal. A-Chem., 229(1-2), 199 (2005)
  23. Dimitratos N, Della Pina C, Falletta E, Bianchi CL, Dal Santo V, Rossi M, Catal. Today, 122(3-4), 307 (2007)
  24. Zhong L, Zhang Y, Tang Y, Bai Y, Polyhedron, 22, 2647 (2003)
  25. Alekar NA, Halligudi SB, Rajani R, Gopinathan S, Gopinathan C, React. Kinet. Catal. Lett., 72(1), 169 (2001)