신재생 에너지로서 DME 기술개발 현황

조원준; 김승수; Wonjun Cho; Seung-Soo Kim

Journal of the Korean Industrial and Engineering Chemistry, Vol.20, No.4, 355-362, August, 2009

Export Citation

신재생 에너지로서 DME 기술개발 현황

Current Status and Technical Development for Di-Methyl Ether as a New and Renewable Energy

조원준^†, 김승수 ^{1, †}

한국가스공사 연구개발원 DME 연구개발
¹강원대학교 삼척캠퍼스 화학공학과

Wonjun Cho^†, and Seung-Soo Kim^{1, †}

Korea Gas Corporation R&D Center, Incheon 406-130, Korea
¹Department of Chemical Engineering, Kangwon National University, Samcheok, Gangwon-do 245-711, Korea

E-mail:,

초록

석유를 기반으로 한 연료는 가까운 미래에 고갈될 것이다. 디메틸에테르(Di-methyl Ether, DME)는 청정에너지이며 천연가스,석탄 및 바이오매스 등으로 생산이 가능하다.DME는 분자구조 내에 탄소-탄소 결합이 없는 함산소 연료로 연소시 그을음과 황산화물을 발생하지 않으며, 물리적 특성이 액화석유가스(Liquified Petroleum Gas, LPG)와 매우 유사하여 LPG 유통인프라를 그대로 활용할 수 있다. DME는 세탄값이 55∼60 정도로 높아 디젤 자동차용 연료로도 활용이 가능하다.차세대 청정연료로 혹은 차세대 화학공업 원료물질로 전력생산, 디젤 연료, 가정용 연료 및 연료전지 등에 사용이 가능하다.본 총설에서는DME의 특성, 표준화, 국내외의 기술개발현황, 대체연료로서의 활용에 대해 살펴보고자 한다.

Fuels based on petroleum will eventually run out in the near future. DME (Di-methyl Ether) is a clean energy source that can be manufactured from various raw materials such as natural gas, coal as well as biomass. As DME has no carbon-carbon bond in its molecular structure and is an oxygenate fuel, its combustion essentially generates no soot as well as no SOx. Because the physical properties of DME are similar to those of LPG, the LPG distribution infrastructure can be converted to use with DME. DME has such high cetane number of 55∼60 that it can be used as a diesel engine fuel. Practical use of DME as a next-generation clean fuel or next-generation chemical feedstock is advancing in the fields of power generation, diesel engines, household use, and fuel cells, among others. The purpose of this paper is review the characteristics, standardization, status of research and development in domestic and foreign countries of DME.

Keywords:Di-metyl Ether (DME);alternative fuel;Diesel substitute;Gas-to-Liqud (GTL);Fischer-Tropsch

[References]

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Knottenbelt C, Catal. Today, 71(3-4), 437 (2002)
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Sudiro M, Bertucco A, Energy, in press (2009)
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Arcoumanis C, Bae C, Crookes R, Kinoshita E, Fuel, 87, 1014 (2008)
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Ahlgren S, Baky A, Bernesson S, Nordberg A, Noren O, Hansson PA, Biosystems Engineering, 99, 145 (2008)
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[Referenced By]

[Related Articles]

[1] Fleisch TH, Sills RA, Briscoe MD, Journal of Natural Gas Chemistry, 11, 1 (2002)

[2] Knottenbelt C, Catal. Today, 71(3-4), 437 (2002)

[3] van Vliet OPR, Faaij APC, Turkenburg WC, Energy Conversion and Management, 50, 855 (2009)

[4] Sudiro M, Bertucco A, Energy, in press (2009)

[5] van der Drift A, Boerrigter H, Synthesis gas from biomass for fuels and chemicals, ECN-C-06-001 (2006)

[6] Huber GW, Iborra S, Corma A, Chemical Reviews, 1 (2006)

[7] Logdberg S, Development of Fischer-Tropsch Catalysts for Gasified Biomass, Ph.D. Dissertation, KTH School of Chemical Science and Engineering, Sweden (2007)

[8] Fleisch TH, Sills RA, Briscoe MD, Journal of Natural Gas Chemistry, 11, 1 (2002)

[9] Semelsberger TA, Borup RL, Greene HL, J. Power Sources, 156(2), 497 (2006)

[10] Arcoumanis C, Bae C, Crookes R, Kinoshita E, Fuel, 87, 1014 (2008)

[11] Aoki S, Inoue N, Ohno Y, 4th Asian DME Conference, Kitakyushu, Fukuoka, Japan, 123 (2007)

[12] Gardmark TL, 4th Asian DME Conference, Kitakyushu, Fukuoka, Japan, 139 (2007)

[13] Japan DME Forum, DME Handbook (2007)

[14] Arcoumanis C, Bae C, Crookes R, Kinoshita E, Fuel, 87, 1014 (2008)

[15] Takeshita T, Yamaji K, Energy Policy, 36, 2773 (2008)

[16] Ahlgren S, Baky A, Bernesson S, Nordberg A, Noren O, Hansson PA, Biosystems Engineering, 99, 145 (2008)

[17] http://www.kogas.re.kr/organization/dme/dme1.jsp

[18] Arcoumanis C, Bae C, Crookes R, Kinoshita E, Fuel, 87, 1014 (2008)

[19] Ohno Y, Yohsida M, Shikada T, Inokoshi O, Ogawa T, Inoue N, JEF Technical report, 8, 34 (2006)

[20] Albertazzi S, Basile F, Brandin J, Einvall J, Hulteberg C, Fornasari G, Rosetti V, Sanati M, Trifiro F, Vaccari A, Catalysis Today, 106, 297 (2006)

[21] http://www.cheric.org/research/kdb/hcprop/showprop.php?cmpid=3

[22] Marchionna M, Ratrini R, Danfilippo D, Migliavacca G, Fuel Processing Technology, 89, 1255 (2008)

[23] 한국석유관리원 내부자료 (2007)

[24] 석유 및 석유대체연료사업법 (2007)

[25] http://www.dailycosmetic.com/Contents/Section/viewNews.asp?item_seq=35700

[26] http://www.koreadme.com/index.htm

[27] 백영순, 한국에너지공학회 추계 학술발표 논문집, 52 (2005)

[28] Chang JS, Park MS, Jhung SH, Park SE, J. Korean Ind. Eng. Chem., 14(6), 689 (2003)

[29] 전기원, 장종산, 이재훈, Chemical Industry and Technology, 17, 117 (1999)

[30] Cho W, Ju WS, Lee SH, Kim BJ, Lee KJ, Yan YB, Baek YS, 2nd Asian DME Conference, 141 (2005)

[31] Cho W, Baek Y, Oh Y, Lee S, Ju W, Song T, 3rd Asian DME Conference, Shanghai, China, 55 (2006)

[32] http://www.kogas.re.kr/organization/dme/dme1.jsp

[33] Pyo Y, Kwon O, Kim G, Yu S, Ryu J, Lee Y, 2008 한국 자동차공학회 창립 30주년 기념 학술대회 논문집, 433 (2008)

[34] 오전근, 방진환, News & Information for Chemical Engineering, 20, 533 (2002)

[35] Korea Patent 10-2002-0049565 (2002)

[36] Ohno Y, Yagai H, Inoue N, Lkuyama K, Aoki S, Natural Gas Conversion: Proceedings of the 8th Natural Gas Conversion Symposium, Natal, Brazil, 1 (2007)

[37] du Bourg HDM, 23rd World Gas Conference, Amsterdam, Netherlands (2006)

[38] http://www.cheric.org/PDF/NICE/NI23/NI23-6-0651.pdf

[39] Ogawa T, Inoue N, Shikada T, Ohno Y, Journal of Natural Gas Chemistry, 12, 219 (2003)

[40] http://www.fueldme.com/news_e.html

[41] http://eficlient.kma.net/EFIClient/files/ccLibraryFiles/Filename/000000000809/2008_WCTL_Zhen&Taupy.pdf

[42] Weidou N, 4th Asian DME Conference, Kitakyushu, Fukuoka, Japan, 15 (2007)

[43] http://www.biodme.eu/doc/BioDME_ShortPresentation_dec2008.pdf

[44] http://www.risiinfo.com/technologyarchives/chemicals/Swedish-Energy-Agency-provides-grant-for-renewable-DME-plant.html

[45] http://www.todayenergy.kr/news/articleView.html?idxno=42461

[46] Tijm PJA, Heydorn EC, Diamond BW, 1999 Gasification Technologies Conference, San Francisco, California, USA (1999)