Adsorption of 2,4-dichlorophenol on metal-nitrate modified activated carbon

Kanagasabai Muruganandam Ponvel; Dhamodaran Kavitha; Kyung-Min Kim; Chang-Ha Lee

Korean Journal of Chemical Engineering, Vol.26, No.5, 1379-1382, September, 2009

DOI10.1007/s11814-009-0217-4 Export Citation

Adsorption of 2,4-dichlorophenol on metal-nitrate modified activated carbon

Kanagasabai Muruganandam Ponvel, Dhamodaran Kavitha, Kyung-Min Kim, and Chang-Ha Lee^†

Department of Chemical and Biomolecular Engineering, Yonsei University, 262 Sungsanno Seodaemun-gu, Seoul 120-749, Korea

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To remove 2,4-dichlorophenol (2,4-DCP) from aqueous solution, the surface of the activated carbon was first treated with HCl and then the surface was modified by using various metal ions (Cu, Co, Fe, Ni, Zn, and Mg). Metal doping significantly enhanced the adsorption efficiency of activated carbon, an effect that was further increased by HCl treatment of the modified activated carbons. Of all the preparations, the zinc(II)-modified activated carbon with HCl treatment showed the highest adsorption capacity for 2,4-DCP. Analysis of the zinc(II)-modified activated carbon by SEM and BET showed a surface area and micropore volume of around 1,154.69 m2/g and 0.291 cm3/g, respectively, values about 20% higher than in the starting material. In the pH range of 2.0-11.0, the maximum uptake of 2,4-DCP from an initial concentration of 1,000 mg/L was 508 mg/g at pH 4.0.

Keywords:Activated Carbon Modification;2,4-Dichlorophenol;Adsorption;Metal Ions;Metal-doped Activated Carbon

[References]

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Jung MW, Ahn KH, Lee Y, Kim KP, Rhee JS, Park JT, Paeng KJ, Microchemical Journal, 70, 123 (2001)
Zumriye A, Yener J, Waste Manage., 21, 695 (2001)
Banat F, Al-Asheh S, Al-Makhadmeh L, Chem. Eng. Technol., 27(1), 80 (2004)
Patterson JW, Industrial waste water treatment technology, Ann Arbor Science Publication Inc, Ann Arbor, MI (1985)
Mohanty K, Das D, Biswas MN, Chem. Eng. J., 115(1-2), 121 (2005)
Kwon JM, Moon JH, Bae YS, Lee DG, Sohn HC, Lee CH, ChemSusChem., 1, 307 (2008)
Bae YS, Kim MB, Lee HJ, Lee CH, Ryu JW, AIChE J., 52(2), 510 (2006)
Caturla F, Martin-Martinez JM, Molina-Sabio M, Rodriguez-Reinoso F, Torregrosa R, J. Colloid. Interf. Sci., 124, 528 (1988)
Chern JM, Chien YW, Water Res., 37, 2347 (2003)
Dvorak BI, Lawler DF, Speitel GE, Jones DL, Badway DA, Water Environ. Res., 65, 827 (1993)
Lin SH, Cheng MJ, Waste Manage., 22, 595 (2002)
Streat M, Patrick JW, Perez MJC, Water Res., 29, 467 (1995)
Kim SJ, Shim WG, Kim TY, Moon H, Kim SJ, Cho SY, Korean J. Chem. Eng., 19(6), 967 (2002)
Stoeckli F, Hugi-Cleary D, Russ. Chem., B50, 2060 (2001)
Dabrowski A, Podkooecielny P, Hudicki Z, Barczak M, Chemosphere, 58, 1049 (2005)
Villacanas F, Pereira MFR, Orfao JJM, Figueiredo JL, J. Colloid Interface Sci., 293(1), 128 (2006)
Lazlo K, Coloids. Surf. A: Physicochem. Eng. Aspects, 265, 32 (2005)
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Stavropoulos GG,. Samaras P. Sakellaropoulos GP, J. Hazard. Mater., 151, 414 (2008)
Lee HC, In JH, Lee SY, Kim JH, Lee CH, J. Supercrit. Fluids, 36(1), 59 (2005)
Mugisidi D, Ranaldo A, Soedarsono JW, Hikam M, Carbon, 45, 1081 (2007)
Rodriguez-Reinoso F, Molina-Sabio M, Carbon, 30, 1111 (1992)
Ganan-Gomez J, Macias-Garcia A, Diaz-Diez MA, Gonzalez-Garcia C, Sabio-Rey E, Appl. Surf. Sci., 252(17), 5976 (2006)
Nevskaia DM, Santianes A, Munoz V, Guerrero-Ruiz A, Carbon, 37, 1065 (1999)
Goud VV, Mohanty K, Rao MS, Jayakumar NS, Chem. Eng. Technol., 28, 817 (2005)

[Referenced By]

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[3] Zumriye A, Yener J, Waste Manage., 21, 695 (2001)

[4] Banat F, Al-Asheh S, Al-Makhadmeh L, Chem. Eng. Technol., 27(1), 80 (2004)

[5] Patterson JW, Industrial waste water treatment technology, Ann Arbor Science Publication Inc, Ann Arbor, MI (1985)

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[10] Chern JM, Chien YW, Water Res., 37, 2347 (2003)

[11] Dvorak BI, Lawler DF, Speitel GE, Jones DL, Badway DA, Water Environ. Res., 65, 827 (1993)

[12] Lin SH, Cheng MJ, Waste Manage., 22, 595 (2002)

[13] Streat M, Patrick JW, Perez MJC, Water Res., 29, 467 (1995)

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[15] Stoeckli F, Hugi-Cleary D, Russ. Chem., B50, 2060 (2001)

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