An ab initio study of the interactions between H2O and Cl-2(+) and H2O and Br-2(+) has been performed. We present calculations using both the UMP2 level and the UCCSD(T) level of correlation with the aug-cc-pVTZ basis. The aug-cc-pVQZ basis was tested for selected geometries and was found to yield results similar to the smaller basis. For the H2O-Cl-2(+) cation, a C-2 nu structure has been identified as the minimum, with D-e = 6500 cm(-1) (78 kJ/mol). A low-lying excited state has D-e = 6000 cm(-1) (72 kJ/mol). The adiabatic and vertical ionization energies of the complex are 10.7 and 11.0 eV, compared to the experimental adiabatic value, 11.5 eV, for free chlorine. For the H2O-Br-2(+) cation, the calculations are more subtle due to second-order Jahn-Teller effects and result in a C-s structure at the minimum, with D-e = 6300 cm(-1) (75 kJ/mol), yielding an adiabatic ionization energy of 9.9 eV compared to the corresponding experimental value, 10.5 eV. for free bromine. The relatively large binding energies give rise to strong normal mode couplings such that the halogen stretching mode becomes mixed with the water bending and other intermolecular modes, resulting in very large frequency shifts. Vertical ionization energies and ion vibrational frequencies also are reported and used to discuss possible experiments to obtain more precise data for each of the complexes.