PAHs made from an odd number of unsaturated carbon atoms and pi electrons (odd PAHs) have been detected in flames and flank the more familiar even PAHs, having approximately the same quantitative importance, particularly for PAHs containing more than 25 carbon atoms. Similarly, soot platelets containing an odd number of carbon atoms can be reasonably assumed to form during combustion. PAHs are intended here as small models for the investigation of some, of their local features. To this end, quantum mechanical calculations were also carried out on periodic models. The spin density patterns were found to be highly dependent on the PAH size and shape. PAHs and soot, once released in the environment, can undergo several oxidation processes. Ozone is then taken as a probe of the reactivity properties of some internal exposed portions of a platelet. A primary ozonide (PO) corresponds to an energy minimum, but the relevant concerted addition pathway does not exist, because a PO-like saddle point is second-order. The reaction begins with a nonconcerted attack that produces a trioxyl radical (TR). Subsequent O-2 loss from the TR leaves either an epoxide with a pi-delocalized electron or a pi-delocalized oxepine, by cleavage of the ring carbon-carbon bond. The initial doublet spin multiplicity thus provides a description of the reaction surface unlike that for the internal reactivity of the closed-shell even systems investigated in a previous work, even though the final functionalization is the same.