The phase behavior of a single polyethylene chain confined between two adsorption walls is investigated by using molecular dynamics simulations. In the free space, it is confirmed in our calculation that the isolated polymer chain exhibits a dis- ordered coil state at high temperatures, and collapses into a condensed state at low temperatures, that is, the coil-to-globule transition, and the finite chain length effects are considered since the critical region depends on chain lengths. When the chain is 19 confined between two attractive walls, however, the equilibrium properties not only depend on the chain length but also depend on the adsorption energy and the con finement. Mainly, we focus on the influence of polymer chain length, confinement, and adsorption interaction on the equilibrium thermodynamic properties of the polyethylene chains. Chain lengths of N = 40, 80, and 120 beads, distances between the two walls of D = 10, 20, 30, 50, and 90 angstrom, and adsorption energies of w = 1.5, 2.5, 3.5, 6.5, and 8.5 kcal/mol are considered here. By considering the confinement-adsorption interactions, some new folding structures are found, that is, the hairpin structure for short chain of N = 40 beads, and the enhanced hairpin or crystal like structures for long chains of N = 80 and 120 beads. The results obtained in our simulations may provide some insights into the phase behaviors of confined polymers, which can not be obtained by previous studies without considering confinement-adsorption interactions. (c) 2008 Wiley Periodicals, Inc.