화학공학소재연구정보센터
Thin Solid Films, Vol.516, No.7, 1314-1321, 2008
Substitution of transparent conducting oxide thin films for indium tin oxide transparent electrode applications
The present status and prospects for further development of reduced or indium-free transparent conducting oxide (TCO) materials for use in practical thin-film transparent electrode applications such as liquid crystal displays are presented in this paper: reduced-indium TCO materials such as ZnO-In2O3, In2O3-SnO2 and Zn-In-Sn-O multicomponent oxides and indium-free materials such as AI- and Ga-doped ZnO (AZO and GZO). In particular, AZO thin films, with source materials that are inexpensive and non-toxic, are the best candidates. The current problems associated with substituting AZO or GZO for ITO, besides their stability in oxidizing environments as well as the non-uniform distribution of resistivity resulting from do magnetron sputtering deposition, can be resolved. Current developments associated with overcoming the remaining problems are also presented: newly developed AZO thin-film deposition techniques that reduce resistivity as well as improve the resistivity distribution uniformity using high-rate do magnetron sputtering depositions incorporating radio frequency power. In addition, stability tests of resistivity in TCO thin films evaluated in air at 90% relative humidity and 60 degrees C have demonstrated that sufficiently moisture-resistant AZO thin films can be produced at a substrate temperature below 200 degrees C when the film thickness was approximately 200 nm. However, improving the stability of AZO and GZO films with a thickness below 100 nm remains a problem. (c) 2007 Elsevier B.V. All rights reserved.