A solar-powered adsorption air-conditioning system was designed and installed in the green building of Shanghai Research Institute of Building Science. The system contained 150 m(2) solar collectors and two adsorption chillers with nominal refrigeration capacity of 8.5 kW. Based on performance characteristics of the adsorption chiller, the operation mode of the solar-powered air-conditioning system was optimized by maintaining a phase shift of 540 s between the two adsorption chillers. Thereafter, the whole system realized stable operation by the balance of heat consumption and refrigeration output. From June to August of 2005, the solar-powered air-conditioning system continuously ran between 9:00 and 17:00. The operation performance of the system under representative working condition showed that the average refrigeration output of the solar-powered air-conditioning system was 15.3 kW during an 8 h operation and the maximum value exceeded 20 M Solar fraction for the system in summer was 71.7%, which corresponded to the designed cooling load (15 kW). Compared with the ambient temperature, it was deduced that solar radiant intensity had a more distinct influence on the performance of solar-powered air-conditioning system. (C) 2007 Published by Elsevier Ltd.