I applied perspectives on operations research (OR) to propose a non-linear mathematical model, termed the APWs (allocation of pumping wells) model, to address problems associated with allocating pumping rates of a multi-well system for a brackish water reverse osmosis (BWRO) plant. In some and and inshore regions, feed water mostly preferred to exploit groundwater, owing to its easier desalted characteristic than seawater. However, the operations of most multi-well systems are always arbitrary, and we could not guarantee the strategies of operation might be optimal; additionally, the pumping quantity and quality variation of each well would all induce the unstable quality of feed water, and then lead to the problem of scaling. Though adding acid could treat the problem of scaling, the acidification, on the other hand, means the increasing cost and damage risk of a reverse osmosis (RO) system. Therefore, the overriding objective of this study is to decide the optimal allocating pumping rate among wells for a RO system on the premise of no acid added and under finite groundwater resources, to ensure feed water has no scaling potential and achieve marginal usage of groundwater resources. The APWs model tries to integrate engineering and management aspects to replace subjective operation of a multi-well system. Here, I apply scaling intensity (SI) proposed by literature that considered calcium carbonate (CaCO3), calcium sulfate (CaSO4) and silica (SiO2) as mainly potential scaling compounds in feed water to assess the scaling potential of a RO system. Besides, I present a solving algorithm for achieving the maximal SI with no scaling occurred. Moreover, I apply the proposed model to a case study in Taiwan by considering four-well system, to obtain optimal allocation with retaining the cleanest residual storage of whole groundwater resources, to avoid the waste of water resources. The results shown that through the assistance of OR technique, it could provide helpful information indeed in RO feed water management. In a word, the APWs model proposed in this paper not only could provide referenced guidelines for all RO operators all over the world, but also allow engineers to gain new insights into their field by integrating different disciplines.