This paper presents a two-stage solar multi-effect humidification dehumidification desalination process plotted from pinch analysis. The sketch of two-stage solar multi-effect humidification dehumidification desalination process is given. The solar vacuated tube collector is employed in the desalination system, multi-effect humidification dehumidification desalination (HDD) process are plotted two different temperature range according to pinch technology. The higher temperature range is from 60 to 80 degrees C, and the lower is from 30 to 60 degrees C. The mass flow rates of dry air in the two stage desalination units are different. The pinch analysis chart is given. According to the pinch chart, the energy recover rate could get higher according to working temperature range. The research proves that the multi-effect HDD has much room to be improved.