가교폴리(4-비닐피리딘)과 메틸오렌지와의 결합에 대한 특이한 온도의존성 8. 가교체 성질의 영향

이석기; 김우식

Polymer(Korea), Vol.21, No.5, 725-729, September, 1997

Export Citation

가교폴리(4-비닐피리딘)과 메틸오렌지와의 결합에 대한 특이한 온도의존성 8. 가교체 성질의 영향

Peculiar Temperature Dependence the Binding of Methyl Orange by Crosslinked Poly(4-vinylpyridine)

이석기, 김우식

초록

가교폴리(4-비닐피리딘)과 메틸오렌지와의 결합에 미치는 가교제의 영향을 검토하기 위해 N,N'-1,4-페닐렌비스아크릴아미드로 가교된 가교폴리(4-비닐피리딘)을 사용하여 메틸오렌지와 결합실험을 행하였다. 이들의 평형결합량으로부터 일차결합상수(K₁)를 구한 결과, 결합온도 및 가교도에 대한 K₁의 도시는 bell 모야의 곡선을 나타내었다. 본 연구의 결합계의 bell 모양 곡선에서 최대결합량을 나타내는 온도 및 가교도는 이전 연구의 가교폴리(4-비닐피리딘)-메틸오렌지 동족체계와 비교하였을 때 가교제에 따라 달라졌으며, 가교제가 rigid할수록 최대결합량을 나타낸 가교도는 낮아졌다. 이들 결과를 가교제의 rigidity에 따른 가교 hole 크기로 설명아였다.

In order to investigate the effect of crosslinker on the binding of methyl orange by crosslinked poly(4-vinylpyridine), crosslinked poly(4-vinylpyridine) containing N1) were evaluated from equilibrium binding amounts. The plots of K₁ against the binding temperature and the degree of crosslinking showed bell-shaped curves. When the temperature and the degree of crosslinking of maximum binding in the bell-shaped curves of this binding system were compared with those of previous binding systems of crosslinked poly (4-vinylpyridines)-methyl orange, they were varied with crosslinked poly(4- vinylpyridines) containing different crosslinkers. And the degree of crosslinking for the maximum binding was lowered with increasing the rigidity of crosslinker. These results could be explained in terms of the crosslinked hole sixte with the rigidity of crosslinker.

Keywords:plenylendbisacrylamide;crosslimked poly(4-vinylpyridine);methyl orange;binding;bell-shaped curve;crosslinked hole size

[References]

Nagwekar JB, Muangnoicharoen NJ, J. Pharm. Sci., 62, 1439 (1973)
Takagishi T, Takami K, Kuroki N, J. Polym. Sci. A: Polym. Chem., 12, 1919 (1974)
Takagish T, Fijii S, Kuroki N, J. Polym. Sci. A: Polym. Chem., 20, 221 (1982)
Kozuka K, Takagish T, Hamano H, Kuroki N, J. Polym. Sci. A: Polym. Chem., 23, 1243 (1985)
Takagishi T, Shibano M, Lim YJ, J. Polym. Sci. A: Polym. Chem., 25, 2584 (1987)
Kozuka H, Hosokawa T, Takagish T, J. Polym. Sci. A: Polym. Chem., 27, 555 (1989)
Kim WS, Seo KH, Hwang YY, Lee JK, J. Polym. Sci. C: Polym. Lett., 26, 347 (1988)
Kim WS, Lee SK, Seo KH, Polym.(Korea), 14(2), 146 (1990)
Lee SK, Seo KH, Kim WS, Polymer, 34, 2392 (1993)
Kim WS, Lee SK, Seo KH, Macromol. Chem. Phys., 195, 449 (1994)
Lee SK, Park NK, Kim WS, J. Korean Ind. Eng. Chem., 1(2), 182 (1990)
Kim WS, Lee SK, Lim YJ, J. Korean Fiber Soc., 31, 725 (1994)
Perrin DD, Armarego WLF, "Purification of Laboratory Chemicals," 2nd ed., Pergamon Press, New York (1980)
Klotz IM, Walter F, Pivan R, J. Am. Chem. Soc., 68, 1486 (1946)

[Referenced By]

[1] Nagwekar JB, Muangnoicharoen NJ, J. Pharm. Sci., 62, 1439 (1973)

[2] Takagishi T, Takami K, Kuroki N, J. Polym. Sci. A: Polym. Chem., 12, 1919 (1974)

[3] Takagish T, Fijii S, Kuroki N, J. Polym. Sci. A: Polym. Chem., 20, 221 (1982)

[4] Kozuka K, Takagish T, Hamano H, Kuroki N, J. Polym. Sci. A: Polym. Chem., 23, 1243 (1985)

[5] Takagishi T, Shibano M, Lim YJ, J. Polym. Sci. A: Polym. Chem., 25, 2584 (1987)

[6] Kozuka H, Hosokawa T, Takagish T, J. Polym. Sci. A: Polym. Chem., 27, 555 (1989)

[7] Kim WS, Seo KH, Hwang YY, Lee JK, J. Polym. Sci. C: Polym. Lett., 26, 347 (1988)

[8] Kim WS, Lee SK, Seo KH, Polym.(Korea), 14(2), 146 (1990)

[9] Lee SK, Seo KH, Kim WS, Polymer, 34, 2392 (1993)

[10] Kim WS, Lee SK, Seo KH, Macromol. Chem. Phys., 195, 449 (1994)

[11] Lee SK, Park NK, Kim WS, J. Korean Ind. Eng. Chem., 1(2), 182 (1990)

[12] Kim WS, Lee SK, Lim YJ, J. Korean Fiber Soc., 31, 725 (1994)

[13] Perrin DD, Armarego WLF, "Purification of Laboratory Chemicals," 2nd ed., Pergamon Press, New York (1980)

[14] Klotz IM, Walter F, Pivan R, J. Am. Chem. Soc., 68, 1486 (1946)