화학공학소재연구정보센터
Chemistry Letters, Vol.37, No.2, 128-133, 2008
Making stable radicals of heavy elements of groups 14 and 13: The might of silyl substitution
Recent developments in the field of stable free radicals centered on the heavy elements of groups 14 and 13, neutral and charged, are covered in this review. The diagnostic geometrical characteristics and bonding features of the title species are presented. The thermodynamic and kinetic factors, affecting the stability and electronic configuration of radicals, are also discussed, with particular emphasis being given to the stabilizing influence of the bulky silyl substituents.