Fluid Phase Equilibria, Vol.103, No.1, 41-50, 1995
Calculating One-Component Vapor-Liquid-Equilibria Using Equations of State - A New Temperature-Dependence for the Attractive Term in the Christoforakos-Franck Equation
A new temperature-dependence is proposed for the depth of the square-well parameter in the Christoforakos-Franck equation of state. A comparison of theory with experiment is reported for the vapour-liquid equilibria of 30 one-component fluids including the noble gases, alkanes, cyclic hydrocarbons, ketones, alkanols and chlorocarbons, which indicates that the modified equation can be accurately employed at sub-critical conditions. The results are also compared with available data for the simplified perturbed hard-chain theory equation of state.
Keywords:HARD-CHAIN THEORY;ORGANIC OXYGEN COMPOUNDS;BINARY FLUID MIXTURES;THERMODYNAMIC PROPERTIES;PHASE-EQUILIBRIA;HIGH-PRESSURES;PVT SURFACE;WATER;HYDROCARBONS;MOLECULES