화학공학소재연구정보센터
Industrial & Engineering Chemistry Research, Vol.47, No.9, 3274-3284, 2008
Seamless mass transfer correlations for packed beds bridging random and structured packings
A unifying correlative approach for the gas-liquid mass transfer in both structured- and random-packing containing towers was developed based on a two-correlation kernel. Two databanks consisting of 861 experiments for structured packings and 4291 experiments for random packings were merged and concerned the volumetric local and overall gas- and liquid-side mass transfer coefficients k(G)a(w), k(L)a(w), K(G)a(w), and K(L)a(w), the effective gas-liquid interfacial area, a(w), and the height equivalent to a theoretical plate, HETP. The three-phase systems were representative of absorption, desorption and distillation applications. Two correlations have emerged, the first to evaluate the local gas- or liquid-side mass transfer coefficient (k(gamma)), the second to correlate the effective gas-liquid interfacial area (a(w)). A reconciliation method was used to calibrate and validate the two-correlation kernel (k(gamma),a(w)) owing to a broad domain of applicability and embracing indifferently both structured- and random-packing columns. The results proved satisfactory and statistical analysis yielded, respectively, 22.1% and 17.6% for the mean and standard deviation for the absolute relative error (ARE) regarding the mass transfer parameters applicable to structured packings. These correlations had also the capacity to predict the same parameters for the random packings with a mean and standard deviation for ARE, respectively, of 26.3% and 24.4%.