Inorganic Chemistry, Vol.47, No.6, 1904-1906, 2008
Thermal rearrangement of Phosphine-B(C6F5)(3) adducts
A series of tertiary and secondary phosphine-B(C6F5)(3) adducts are shown to undergo facile, thermal-induced rearrangement to give zwitterionic species of the form R3P(C6F4)BF(C6F5)(2) and R2PH(C6F4)BF(C6F5)(2), respectively.