Inorganic Chemistry, Vol.47, No.11, 4656-4660, 2008
Gd7I12Zn: A group 12 atom in the octahedral Gd-6 cluster
The title compound was synthesized from Gd, GdI3 and Zn under Ar atmosphere at 850 degrees C. It crystallizes in the space group F (3) over bar (No. 148) with lattice constants a = 15.686(1) angstrom and c = 10.4882(8) angstrom. The structure features isolated Zn-centered Gc(16) octahedra with all edges and corners capped by I atoms. The disorder of the Gd atoms is rationalized via electron microscopic techniques. A computational analysis using the extended Huckel method has been carried out in order to understand the bonding of this compound. The structure of isotypic La7I12Co is also remarked (a = 16.040(1) angstrom and c = 10.905(2) angstrom).