The Reynolds analogy concept has been used in almost all turbulent reacting flow RANS (Reynolds-averaged Navier-Stokes) simulations, where the turbulence scalar transfers in flow fields are calculated based on the modeled turbulence momentum transfer. This concept, applied to a diffusion flame model combustor, is assessed in this paper. Some of the numerical results, obtained from a flamelet combustion model with the turbulent Prandtl/Schmidt number varying from 0.25 to 0.85, are presented and compared with a benchmark experimental database. It is found that the turbulent Prandtl/Schmidt number has significant effects on the predicted temperature and species fields in the combustor. This is also true for the temperature profile along the combustor wall. In contrast, its effect on the velocity field is insignificant in the range considered. With an optimized turbulent Prandtl/Schmidt number, both velocity and scalar fields can be reasonably and quantitatively predicted. For the present configuration and operating conditions, the optimal Prandtl/Schmidt number is 0.5, lower than the traditionally used value of similar to 0.85. This study suggests that for accurate prediction of turbulence scalar transfers in practical reacting flows, the Reynolds analogy concept should be improved and new approaches should be developed. Crown Copyright (C) 2007 Published by Elsevier Ltd. All rights reserved.