화학공학소재연구정보센터
Journal of Applied Polymer Science, Vol.109, No.1, 483-491, 2008
Structures and properties of ternary blends of recycled poly(ethylene terephthalate)/bisphenol-A polycarbonate/(E/nBA/GMA)
Recycled poly(ethylene terephthalate)/ bisphenol-A polycarbonate/PTW (ethylene, butylacrylate (BA), and glycidylmethacrylate (E/nBA/GMA) terpolymer) were blended in different sequence through low temperature solid state extrusion (LTSSE) was studied. R-PET/PC blends were toughened by PTW, resulting in the improvement of impact strengths. In tensile test, the (PC/PTW)/r-PET blends made by mixing r-PET with the preblend of PC/PTW had noticeable strengthening effect on its tensile properties, which was not impaired by the rubber content due to its strain-hardening occurred following its necking at the constant load. Morphological study by scanning electron microscopy (SEM) was in conformity with the mechanical result. For the (PC/PTW)/r-PET blends, the PC particles were well embedded in the PET matrix and the smooth morphology exhibited. The DSC thermographs for heating and cooling run indicated that the crystallinity of PET rich phase was affected by different blending sequence. In the FTIR test, the different absorption intensity of PC aromatic carbonate carbonyl band was clearly illustrated. The results indicated different blending sequence led to different blending effect. (c) 2008 Wiley Periodicals, Inc.