A systematic study on the structure and stability of nitrate anion hydrated clusters, NO3-center dot nH(2)O (n = 1-8) are carried Out by applying first principle electronic structure methods. Several possible initial structures are considered for each size cluster to locate equilibrium geometry by applying a correlated hybrid density functional with 6-311++G(d,p) basis function. Three different types of arrangements, namely, symmetrical double hydrogen bonding, single hydrogen bonding and inter-water hydrogen bonding are obtained in these hydrated clusters. A structure having inter-water hydrogen bonding is more stable compared to other arrangements. Surface structures are predicted to be more stable over interior structures. Up to five solvent H2O molecules can stay around solute NO3- anion in structures having an inter-water hydrogen-bonded cyclic network. A linear correlation is obtained for weighted average solvent stabilization energy with the size (n) of the hydrated cluster. Distinctly different shifts of IR bands are observed in these hydrated clusters for different kinds of bonding environments of O-H and N = O stretching modes compared to isolated H2O and NO3- anion. Weighted average IR spectra are calculated on the basis of statistical population of individual configurations of each size cluster at 150 K.